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Sku SC45-0148_2_G
US-Strem
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Product Information

Product Name
(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (R,R)-Et-DUPHOS-Rh
Brand Name
US-Strem
Product Number
45-0148
CAS
228121-39-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11239244
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-2-(2R,5R)-2,5-diethylphospholan-1-ylphenyl-2,5-diethylphospholane;rhodium;tetrafluoroborate
InChI Key
XIOPHSBHVOCZMM-KYOOHHHUSA-N
SMILES
B-(F)(F)(F)F.CCC@H1P(C@@H(CC1)CC)C2=CC=CC=C2P3C@@H(CCC@H3CC)CC.C1/C=C\CC/C=C\C1.Rh

Application

Technical Notes:
1.See 15-0097
2.L igand used in asymmetric hydrogenation of 2-methylenesuccinamic acid.
L igand used for the Rh-catalyzed asymmetric hydrogenation of a-aminomethylacrylates .
References :
1. Org. Process Res. Dev., 2003, 7, 407.
2. Proc. Nat!. Acad. Sci., 2007, 104, 16787.