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Sku SC15-0092_2_G
US-Strem
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Product Information

Product Name
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene, min. 98% (S,S)-Me-DUPHOS
Brand Name
US-Strem
Product Number
15-0092
CAS
136735-95-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2734553
IUPAC Name
(2S,5S)-1-2-(2S,5S)-2,5-dimethylphospholan-1-ylphenyl-2,5-dimethylphospholane
InChI Key
AJNZWRKTWQLAJK-VGWMRTNUSA-N
SMILES
CC@H1CCC@@H(P1C2=CC=CC=C2P3C@H(CCC@@H3C)C)C

Description

Technical Notes:
1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetri hydrogenation of
imines, enamines, and enamides.
2. Asymmetric hydrogenation of vinyl alcohols.?
3.Catalyst used for the asymmetric hydrogenation of enol phosphonates.
4. Asymmetric hydrogenation of allylic alcohols
5. Ligand for the catalytic as ymmetric 4+1 cycloaddition of vinylallenes with co.
6.Ligand for the Rh-catalyzed as ymmetric enyne cycloisomerization
7. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
8.Palladium-catalyzed asymmetric phos phination.
9.Palladium catalyzed asymmetric hydrog enation of carbonyls. 10
10.Palladium-catalyzed 1,4 arylation of a, ß-uns aturated ketones.
11.As ymmetric, Ir-catalyzed, 2+2+2 cycloaddition.
12.Asymmertric palladium catalyzed synthesis of 2-methyl-indolines via c H activation.'3
13.Copper-catalyzed monoborylation of 1,3-Dienes
14.Rhodium-catalyzed enantios elective trans metalation. , .
15.CuH-catalyzed hydroamination of styrenes. 1

References Data Source From Pubchem

Synthesis of P- and S-Stereogenic Compounds via Enantioselective C–H Functionalization

Publication Name: Synthesis
Publication Date: 2022-05-12
DOI: 10.1055/a-1802-6793

Asymmetric Hydroamination of Aryl-Substituted Alkenes

Publication Name: Science of Synthesis
Publication Date: 2022

Copper-Catalyzed Carboxylation of Dienes

Publication Name: Science of Synthesis
Publication Date: 2022

Recent Developments in Transition-Metal-Catalyzed Asymmetric Hydrogenation of Enamides

Publication Name: Synthesis
Publication Date: 2020-10-20
DOI: 10.1055/s-0040-1705939