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(-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane, 98+% (S,S)-Et-BPE|15-0102|136779-27-6

(-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane, 98+% (S,S)-Et-BPE

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Sku SC15-0102_2_G
US-Strem
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Product Information

Product Name
(-)-1,2-Bis((2S,5S)-2,5-diethylphospholano)ethane, 98+% (S,S)-Et-BPE
Brand Name
US-Strem
Product Number
15-0102
CAS
136779-27-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
15700985
IUPAC Name
(2S,5S)-1-2-(2S,5S)-2,5-diethylphospholan-1-ylethyl-2,5-diethylphospholane
InChI Key
QOLRLVPABLMMKI-XSLAGTTESA-N
SMILES
CCC@H1CCC@@H(P1CCP2C@H(CCC@@H2CC)CC)CC

Description

Technical Notes:
1. Ligand for Ru-catalyzed enantioselective hydrogenation of ene carbamates .
2.Ligand for Pd-catalyzed asymmetric hydrogenation for producing N-acyI enamide.
3.Ligand for Rh-catalyzed regio- and enantioselective asymmetric hydroformylation of olefins .
4.Ligand for Rh-catalyzed enantioselective catalyst for asymmetric hydroformylation of 2.2 1-bicyclic olefins .
References:
1.Tetrahedron: Asymmetry, 2001, 12, 863.
2.Tetrahedron L etters, 2004, 45, 9277.
3.Angew. Chem. Int. Ed., 2005, 44, 5834.
4.Tetrahedron L etters, 2005, 46, 7831.

References Data Source From Pubchem

Cu-Catalyzed Conjugate Addition of Grignard Reagents to Thiochromones: An Enantioselective Pathway for Accessing 2-Alkylthiochromanones
Publication Name: Synlett
Publication Date: 2018-08-02
DOI: 10.1055/s-0037-1610225