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(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE|15-0104|129648-07-3

(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE

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Sku SC15-0104_2_G
US-Strem
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Product Information

Product Name
(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE
Brand Name
US-Strem
Product Number
15-0104
CAS
129648-07-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2734555
IUPAC Name
(2R,5R)-1-2-(2R,5R)-2,5-dimethylphospholan-1-ylethyl-2,5-dimethylphospholane
InChI Key
IRCDUOCGSIGEAI-AAVRWANBSA-N
SMILES
CC@@H1CCC@H(P1CCP2C@@H(CCC@H2C)C)C

Description

Technical Notes:
1. Ligand for Cu- catalyzed enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines to prepare a chiral amines .
2.Used in the Pd-catalyzed allylation of aliphatic alcohols.
3.Ligand for Rh-catalyzed enantioselective carbonyl hydroacylation.
4.Ligand for cobalt-catalyzed asymmetric alkene hydroge nation.
References:
1.J. Am. Chem. Soc., 2003, 125, 1692.
2.J. Org. Chem., 2003, 68, 8092.
3.J. Am. Chem. Soc.. 2008, 130, 2916.
4.Science, 2013, 342, 1076.

References Data Source From Pubchem

Allenylation and Propargylation Reactions of Ketones, Aldehydes, Imines, and Iminium Ions Using Organoboronates and Related Derivatives
Publication Name: Synthesis
Publication Date: 2017-01-18
DOI: 10.1055/s-0036-1588397

Copper-Catalyzed Enantioselective Conjugate Addition to α,β-Unsaturated Aldehydes with Various Organometallic Reagents
Publication Name: Synthesis
Publication Date: 2016-06-28
DOI: 10.1055/s-0035-1562487

Organometallic-Catalysed Gas–Liquid Reactions in Continuous Flow Reactors
Publication Name: Topics in Organometallic Chemistry
Publication Date: 2015
DOI: 10.1007/3418_2015_159

The First C 3-Symmetric P-Stereogenic Diphosphinomethane Trinuclear Palladium Clusters: Synthesis and Characterization
Publication Name: Journal of Cluster Science
Publication Date: 2009-03-05
DOI: 10.1007/s10876-009-0244-7

Rhodium-Promoted Hydrogenation of Alkenes
Publication Name: Science of Synthesis
Publication Date: 2009