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Sku SC15-0104_2_G
US-Strem
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General Details
Product Number 15-0104
CAS # 129648-07-3
Molecular Formula (C6H12)PCH2CH2P(C6H12)
Formula Weight 258.33
Physical Properties
Purity 98+%
Shipping & Stability
Safety Yes

Technical Notes:
1. Ligand for Cu- catalyzed enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines to prepare a chiral amines .
2.Used in the Pd-catalyzed allylation of aliphatic alcohols.
3.Ligand for Rh-catalyzed enantioselective carbonyl hydroacylation.
4.Ligand for cobalt-catalyzed asymmetric alkene hydroge nation.
References:
1.J. Am. Chem. Soc., 2003, 125, 1692.
2.J. Org. Chem., 2003, 68, 8092.
3.J. Am. Chem. Soc.. 2008, 130, 2916.
4.Science, 2013, 342, 1076.