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(+)-1,2-Bis((2R,5R)-2,5-dimethyl­phospholano)ethane, 98+% (R,R)-Me-BPE|15-0104|129648-07-3

(+)-1,2-Bis((2R,5R)-2,5-dimethyl­phospholano)ethane, 98+% (R,R)-Me-BPE

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Sku SC15-0104_500_MG
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Product Information

Product Name
(+)-1,2-Bis((2R,5R)-2,5-dimethyl­phospholano)ethane, 98+% (R,R)-Me-BPE
Brand Name
US-Strem
Product Number
15-0104
CAS
129648-07-3
Certificate of Analysis (COA)​
COA not found

Description

Technical Notes:
1. Ligand for Cu- catalyzed enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines to prepare a chiral amines .
2.Used in the Pd-catalyzed allylation of aliphatic alcohols.
3.Ligand for Rh-catalyzed enantioselective carbonyl hydroacylation.
4.Ligand for cobalt-catalyzed asymmetric alkene hydroge nation.
References:
1.J. Am. Chem. Soc., 2003, 125, 1692.
2.J. Org. Chem., 2003, 68, 8092.
3.J. Am. Chem. Soc.. 2008, 130, 2916.
4.Science, 2013, 342, 1076.