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Sku SC15-0096_500_MG
US-Strem
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Product Information

Product Name
(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene, min.98% (R,R)-Me-DUPHOS
Brand Name
US-Strem
Product Number
15-0096
CAS
147253-67-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2734551
IUPAC Name
(2R,5R)-1-2-(2R,5R)-2,5-dimethylphospholan-1-ylphenyl-2,5-dimethylphospholane
InChI Key
AJNZWRKTWQLAJK-KLHDSHLOSA-N
SMILES
CC@@H1CCC@H(P1C2=CC=CC=C2P3C@@H(CCC@H3C)C)C

Description

Technical Notes:
1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetri hydrogenation of
imines, enamines, and enamides.
2. Asymmetric hydrogenation of vinyl alcohols.?
3.Catalyst used for the asymmetric hydrogenation of enol phosphonates.
4. Asymmetric hydrogenation of allylic alcohols
5. Ligand for the catalytic as ymmetric 4+1 cycloaddition of vinylallenes with co.
6.Ligand for the Rh-catalyzed as ymmetric enyne cycloisomerization
7. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
8.Palladium-catalyzed asymmetric phos phination.
9.Palladium catalyzed asymmetric hydrog enation of carbonyls. 10
10.Palladium-catalyzed 1,4 arylation of a, ß-uns aturated ketones.
11.As ymmetric, Ir-catalyzed, 2+2+2 cycloaddition.
12.Asymmertric palladium catalyzed synthesis of 2-methyl-indolines via c H activation.'3
13.Copper-catalyzed monoborylation of 1,3-Dienes
14.Rhodium-catalyzed enantios elective trans metalation. , .
15.CuH-catalyzed hydroamination of styrenes. 1

References Data Source From Pubchem

Rh-catalyzed double carbonylation of cyclopropenes toward valerolactone derivatives via cleavage of carbon–carbon double bonds

Publication Name: Science China Chemistry
Publication Date: 2025-02-25
DOI: 10.1007/s11426-024-2535-y

Copper-catalysed asymmetric hydroboration of alkenes with 1,2-benzazaborines to access chiral naphthalene isosteres

Publication Name: Nature Chemistry
Publication Date: 2024-04-08
DOI: 10.1038/s41557-024-01505-0

Copper-Catalyzed C–C Bond Formation via Carboxylation Reactions with CO2

Publication Name: C-C Cross Couplings with 3d Base Metal Catalysts
Publication Date: 2023
DOI: 10.1007/3418_2023_82

Alkylphosphonium Salts with a Chiral Binaphthyl Backbone

Publication Name: Science of Synthesis
Publication Date: 2022