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(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane, 98+% (S,S)-Me-BPE|15-0105|136779-26-5

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane, 98+% (S,S)-Me-BPE

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Sku SC15-0105_100_MG
US-Strem
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Product Information

Product Name
(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane, 98+% (S,S)-Me-BPE
Brand Name
US-Strem
Product Number
15-0105
CAS
136779-26-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
5702644
IUPAC Name
(2S,5S)-1-2-(2S,5S)-2,5-dimethylphospholan-1-ylethyl-2,5-dimethylphospholane
InChI Key
IRCDUOCGSIGEAI-XUXIUFHCSA-N
SMILES
CC@H1CCC@@H(P1CCP2C@H(CCC@@H2C)C)C

Description

Technical Notes:
1.Rh-catalyzed, enantioselective asymmetric hydroformylation of 2.2. 1-bicyclic olefins .
2. Pt-catalyzed, enantioselective cycloisomerization for the synthesis of planar-chiral ferrocene derivatives . Cu-catalyzed asymmetric borylallylation of vinyl arenes .
References:
1.Tetrahedron Lett, 2005, 46, 7831 . J. 2.Org. Chem., 2016, 81, 6266.
3.Org. L ett..2017, 19, 6144.

References Data Source From Pubchem

Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes
Publication Name: Nature Communications
Publication Date: 2017-06-01
DOI: 10.1038/ncomms15547

Transition-Metal-Catalyzed Enantioselective Synthesis of Compounds with Non-Centrochirality
Publication Name: Synthesis
Publication Date: 2009-05-14
DOI: 10.1055/s-0029-1216818|10.1055/s-0029-1216988

Asymmetric Hydrogenation
Publication Name: Science of Synthesis
Publication Date: 2005