(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane, min. 95% (R,R)-Ph-BPE|15-0473|528565-79-9

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane, min. 95% (R,R)-Ph-BPE

$399.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-0473_500_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane, min. 95% (R,R)-Ph-BPE
Brand Name
US-Strem
Product Number
15-0473
CAS
528565-79-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11420783
IUPAC Name
(2R,5R)-1-2-(2R,5R)-2,5-diphenylphospholan-1-ylethyl-2,5-diphenylphospholane
InChI Key
VHHAZLMVLLIMHT-YFRBGRBWSA-N
SMILES
C1CC@@H(P(C@H1C2=CC=CC=C2)CCP3C@H(CCC@@H3C4=CC=CC=C4)C5=CC=CC=C5)C6=CC=CC=C6

Application

Technical Notes:
1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric
2.This ligand is highly efficient for the hydrogenation of N-acyl aryl- enamides.
3.Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using 4.Ligand in the rhodium- catalyzed asymmetric hydroformylayion of thioamides
5.Ligand for asymmetric addition of allyl cyanide to kstones 6. Ligand for catalytic enantio- and diastereoselective aldol reaction of thioamides.
7- Organocatalytic 3+2 cycloaddition.
8. Site selective allenylation.
9 Asymmetric Phophonate addition.
10. Hydroboration of enamines.

References Data Source From Pubchem

Catalytic Asymmetric Conjugate Addition of Grignard Reagents
Publication Name: Science of Synthesis
Publication Date: 2024

Recent Advances in Transition-Metal-Catalyzed Asymmetric Functionalization of Enamides
Publication Name: Synthesis
Publication Date: 2022-08-18
DOI: 10.1055/a-1892-5473

Ligand-Controlled Regiodivergent Asymmetric Cu-Catalyzed Carbonyl Addition of Vinyl Heteroarenes
Publication Name: Synfacts
Publication Date: 2022-05-17
DOI: 10.1055/s-0041-1737471

Enantioselective Cobalt-Catalyzed C–H Functionalization
Publication Name: Synthesis
Publication Date: 2022-05-12
DOI: 10.1055/a-1801-2595

Acyclic Quaternary Carbon Stereocenters through Transition-Metal-Catalyzed Enantioselective Functionalization of Unsaturated Hydrocarbons
Publication Name: Synthesis
Publication Date: 2022-03-01
DOI: 10.1055/s-0040-1719899