(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Et-DUPHOS-Rh|45-0149|213343-64-7

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Et-DUPHOS-Rh

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Product Information

Product Name
(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Et-DUPHOS-Rh
Brand Name
US-Strem
Product Number
45-0149
CAS
213343-64-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11006841
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;(2S,5S)-1-2-(2S,5S)-2,5-diethylphospholan-1-ylphenyl-2,5-diethylphospholane;rhodium;tetrafluoroborate
InChI Key
XIOPHSBHVOCZMM-ZCTOJWETSA-N
SMILES
B-(F)(F)(F)F.CCC@@H1P(C@H(CC1)CC)C2=CC=CC=C2P3C@H(CCC@@H3CC)CC.C1/C=C\CC/C=C\C1.Rh

Application

Technical Notes:
1. See 15-0098
2. L igand used in asymmetric hydrogenation of 2-methylenesuccinamic acid.
3.L igand used for the Rh-catalyzed asymmetric hydrogenation of o-aminomethylacrylates.
References:
1.Org. Process Res. & Dev., 2003, 7, 407.
2. Proc. Natl. Acad. Sci., 2007, 104, 16787.