Product Name
(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(II)
Certificate of Analysis (COA)
IUPAC Name
cobalt(2+);2,4-ditert-butyl-6-(1S,2S)-2-(3,5-ditert-butyl-2-oxidophenyl)methylideneaminocyclohexyliminomethylphenolate
InChI Key
ZFWPDJKMASHRPT-PNHSAAKESA-L
SMILES
CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O-)C=NC@H2CCCCC@@H2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O-.Co+2
Technical Notes:
1. Catalyst used in the kinetic resolution of racemic, terminal epoxides yielding a chiral diol and the unreacted enantiomer of the
epoxide
2.Precursor to a Co() catalyst for the kinetic resolution of terminal epoxides with alcohols.
3.Desymmetrization of meso-epoxides with carboxylic acids and fluoride.
4.Catalyst for asymmetric cyclopropanation of styrene
5.catalyst for copolymerization ofCOz and epoxides.
6.Enantioselective intramolecular openings of oxetanes.
References:
1.J. Am. Chem. Soc., 2002, 124, 1307. 2.J. Am. Chem. Soc.. 1999, 121, 6086. 3.Tetrahedron L ett., 1997, 38, 773
4.J. Am. Chem. Soc.. 2010, 132, 3268 5.Adv. Synth. Catal.. 2001, 343, 79.
6.J.Am. Chem. Soc., 2005, 127, 10869.
7.J. Am. Chem. soc., 2009, 131, 2786.
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