(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene), 98% (R,R)-Jacobsen Ligand|07-0316|135616-40-9

(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene), 98% (R,R)-Jacobsen Ligand

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Sku SC07-0316_1_G
US-Strem
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Product Information

Product Name
(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene), 98% (R,R)-Jacobsen Ligand
Brand Name
US-Strem
Product Number
07-0316
CAS
135616-40-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2733339
IUPAC Name
2,4-ditert-butyl-6-(1R,2R)-2-(3,5-ditert-butyl-2-hydroxyphenyl)methylideneaminocyclohexyliminomethylphenol
InChI Key
FYNXDGNCEBQLGC-LOYHVIPDSA-N
SMILES
CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=NC@@H2CCCCC@H2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O

Application

Technical Notes:
1.See_ 27-0525, 25-0300, 13- 5800.
2.A versatile ligand for asymmetric catalysis .(a) Conjugate addition of hydrazoic acid to unsaturated imides.

References Data Source From Pubchem

Catalytic Nozaki-Hiyama-Kishi (NHK) Type Reactions
Publication Name: Science of Synthesis
Publication Date: 2023

Formation of Polyhydroxyurethanes in the Reaction of Carbon Dioxide with Diepoxides and Diamines in the Presence of a Chromium Complex
Publication Name: Kinetics and Catalysis
Publication Date: 2022-09-23
DOI: 10.1134/s0023158422050020

By Zinc-Mediated Addition of Terminal Alkynes
Publication Name: Science of Synthesis
Publication Date: 2022

Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide
Publication Name: Kinetics and Catalysis
Publication Date: 2020-07
DOI: 10.1134/s0023158420030088

Solvent-Free Synthesis of Salen Ligands and Pd(II)– and Cu(II)–Salen Complexes: Their Use in the Oxidation of α-Tetralones to α-Naphthols
Publication Name: Synthesis
Publication Date: 2017-06-27
DOI: 10.1055/s-0036-1588446