(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.|25-0300|138124-32-0

(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.

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Sku SC25-0300_1_G
US-Strem
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Product Information

Product Name
(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)manganese (III) chloride, 98% (R,R)-Jacobsen Cat.
Brand Name
US-Strem
Product Number
25-0300
CAS
138124-32-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
73602790
IUPAC Name
2,4-ditert-butyl-6-(1R,2R)-2-(3,5-ditert-butyl-2-oxidophenyl)methylideneaminocyclohexyliminomethylphenolate;manganese(3+);chloride
InChI Key
LJVAWOSDJSQANR-SEILFYAJSA-K
SMILES
CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O-)C=NC@@H2CCCCC@H2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O-.Cl-.Mn+3

Application

Technical Notes:
1.Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
2.Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corres ponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
3.As ymmetric Kinetic res olution of secondary alcohols in water.
4.Enantios elective Reformatsky reaction with ketones.
References:
1.J. Org. Chem.. 1993, 58, 6939.
2.J. Am. Chem. Soc., 1994, 116, 6937
3.Encyclopedia of Reagents for Organic Synthesis, 1995, 7, 4585.
4.Angew. Chem. Int. Ed. Eng., 2003, 42, 1042.
5.Angew. Chem. Int. Ed. Eng., 2006, 45, 2951.

References

Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.