(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride|24-0850|164931-83-3

(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride

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Sku SC24-0850_5_G
US-Strem
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Product Information

Product Name
(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)chromium(III) chloride
Brand Name
US-Strem
Product Number
24-0850
CAS
164931-83-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
135572260
IUPAC Name
2,4-ditert-butyl-6-(1R,2R)-2-(3,5-ditert-butyl-2-hydroxyphenyl)methylideneaminocyclohexyliminomethylphenol;trichlorochromium
InChI Key
ABSDVGHEFTVUQG-ZYOJYBKFSA-K
SMILES
CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=NC@@H2CCCCC@H2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O.ClCr(Cl)Cl

Application

Technical Notes:
1. Catalyst for the asymmetric ring-opening of meso epoxides and for the kinetic resolution of terminal epoxides. 2. Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
3. Catalyst for copolymerization of CO2 and epoxides
4. Catalyst for enantioselective alkylation of tributyltin enolates.
5. Enantioselective addition of Me,Zn to aldehydes.
6. Enantioselective intramolecular addition of tertiary enamides to ketones.
7. Asymmetric iodocyclization.
8. Catalytic intermolecular linear allylic C-H anima tion.
9. Cocatalyst for enantioselective ring opening of epoxides with fluoride .