Product Name
(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene), 98% (S,S)-Jacobsen Ligand
Certificate of Analysis (COA)
IUPAC Name
2,4-ditert-butyl-6-(1S,2S)-2-(3,5-ditert-butyl-2-hydroxyphenyl)methylideneaminocyclohexyliminomethylphenol
InChI Key
FYNXDGNCEBQLGC-KYJUHHDHSA-N
SMILES
CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=NC@H2CCCCC@@H2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O
T echnical Notes:
1.See_ 27-0525,_ 25-0300, 13- 5800.
2.A vers atile ligand for as ymmetric catalysis.（a) Conjugate addition of hydrazoic acid to uns aturated imides .
References:
1.J. Am. Chem. Soc., 1999, 12 1, 8959.
2.J. Am. Chem. Soc., 1999, 121, 3968.
3.Tetrahedron L ett., 1997, 38, 1 693.
4.J. Org. Chem., 1998, 63, 403.
5.Angew. Chem. Int. Ed., 1999, 38, 3357 .
6.J. Am. Chem. Soc., 2004, 126, 9928.
7.J. Am. Chem. Soc., 2003, 125, 4442. 8.Angew. Chem. Int. Ed., 2008, 47, 388.
9.Chem. L ett., 2010, 39, 466.
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