(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat.|25-0301|135620-04-1

(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat.

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Sku SC25-0301_5_G
US-Strem
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Product Information

Product Name
(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)manganese(III) chloride, 98% (S,S)-Jacobsen Cat.
Brand Name
US-Strem
Product Number
25-0301
CAS
135620-04-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
135742506
IUPAC Name
2,4-ditert-butyl-6-(1S,2S)-2-(3,5-ditert-butyl-2-hydroxyphenyl)methylideneaminocyclohexyliminomethylphenol;manganese(3+);trichloride
InChI Key
VGAJDQCIDNCJQC-FTKQXCDWSA-K
SMILES
CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=NC@H2CCCCC@@H2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O.Cl-.Cl-.Cl-.Mn+3

Application

Technical Notes:
1. Catalyst for the conversion of olefins to chiral epoxides in high en antiomeric excess.
2. Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
3.As ymmetric Kinetic resolution of s econdary alcohols in water.
4.Enantios elective Reformatsky reaction with ketones.
References :
1. J. Org. Chem.. 1993.58, 6939.
2. J. Am. Chem. Soc., 1994, 116, 6937.
3. Encyclopedia of Reagents for Drganic Synthesis, 1995, 7, 4585. 4. Angew. Chem. Int. Ed. Eng., 2003, 42, 1042.
5. Angew. Chem. Int. Ed. Eng., 2006, 45, 2951.