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(S)-(-)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenyl­phosphino)-1,1'-biphenyl, min. 95% (S)-Cl-MeO-BIPHEP|15-1056|185913-98-8

(S)-(-)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenyl­phosphino)-1,1'-biphenyl, min. 95% (S)-Cl-MeO-BIPHEP

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Sku SC15-1056_250_MG
US-Strem
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Product Information

Product Name
(S)-(-)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenyl­phosphino)-1,1'-biphenyl, min. 95% (S)-Cl-MeO-BIPHEP
Brand Name
US-Strem
Product Number
15-1056
CAS
185913-98-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
5165044
IUPAC Name
4-chloro-2-(3-chloro-6-diphenylphosphanyl-2-methoxyphenyl)-3-methoxyphenyl-diphenylphosphane
InChI Key
GCBRCSSVOVNEIX-UHFFFAOYSA-N
SMILES
COC1=C(C=CC(=C1C2=C(C=CC(=C2OC)Cl)P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6)Cl

Description

Technical Notes:
1. Ligand used in the ruthenium catalyzed, enantioselective hydrogenation of alkenes, carbonyls,
and imines.
2.Ligand used in the rhodium-catalyzed cyclization of acetylenic aldehydes .
3. Ligand used in the iridium-c atalyzed hydrogenative coupling of alkynes to aromatic and aliphatic N-arylsulfonyl aldimines.
4.Asymmetric Cu catalyzed propargylic substitution with amines,a and enamines.
5.Catalytic desymmetrizing intramolecular Heck reaction.
6.Assembly of 1,3-polyols.
7.Pd-catalyzed diastereo/enantios elective allylic alkylations of ketone enolates .
8.Enantios elective vinylogous R eformatsky-type addition.
9. Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron- substituted allylcopper complexes
and their In situ site-, diastereo-, and enantios elective additions to ketones .

References Data Source From Pubchem

Chelation enables selectivity control in enantioconvergent Suzuki–Miyaura cross-couplings on acyclic allylic systems
Publication Name: Nature Chemistry
Publication Date: 2024-02-08
DOI: 10.1038/s41557-023-01430-8

Synthesis from Diynes and Ethyl Glyoxalate
Publication Name: Science of Synthesis
Publication Date: 2023

Synthesis from Diynes and α-Oxo Aldehydes
Publication Name: Science of Synthesis
Publication Date: 2023

Enantioselective Synthesis of Tetrahydrofurans via a Palladium-Catalyzed [3+2] Cycloaddition
Publication Name: Synfacts
Publication Date: 2022-11-17
DOI: 10.1055/s-0042-1753070

Asymmetric Propargylic Substitution Enabled by Synergistic Nickel and Chiral Anion Catalysis
Publication Name: Synfacts
Publication Date: 2022-02-16
DOI: 10.1055/s-0041-1737859