Product Added to Cart!
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%|15-0156|133545-24-1

(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%

$99.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-0156_100_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Brand Name
US-Strem
Product Number
15-0156
CAS
133545-24-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
22173705
IUPAC Name
2-2-bis(4-methylphenyl)phosphanyl-6-methoxyphenyl-3-methoxyphenyl-bis(4-methylphenyl)phosphane
InChI Key
DTMVLPFJTUJZAY-UHFFFAOYSA-N
SMILES
CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=CC=CC(=C3C4=C(C=CC=C4P(C5=CC=C(C=C5)C)C6=CC=C(C=C6)C)OC)OC

Description

Technical Notes:
In many respects the catalytic profile of the Me BIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PRz group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various c=o, C=c and C=N bonds and several synthetically useful C-c coupling reactions.
1. See 15-0042
2.Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
3. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
4. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
5.Conjugate addition using 2-heteroaryl titanates and zinc reagents .
References:
1. Adv. Synth. C atal., 2004, 346, 842.
2.Org. Lett., 2006, 8, 4573.
3.Org. Process Res. Devel., 2001, 5, 438.
4.J. Am. C hem. Soc., 2003, 125, 10536.
5.Org. L ett., 2009, 1 1, 4200.