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Sku SC15-0145_250_MG
US-Strem
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Product Information

Product Name
2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, 98% BIPHEP
Brand Name
US-Strem
Product Number
15-0145
CAS
84783-64-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2734940
IUPAC Name
2-(2-diphenylphosphanylphenyl)phenyl-diphenylphosphane
InChI Key
GRTJBNJOHNTQBO-UHFFFAOYSA-N
SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6

Description

Technical Notes:
1. Supporting ligand in a chiral diamine ruthenium system for the enantiosele ctive hyd rogenation of ketones.
2. Useful ligand for palladium-catalyzed amination and Kumada cross coupling reactions
3.Useful ligand for palladium-catalyzed synthesis of butatrenes.
4.Useful ligand for iridium-catalyzed c-c cross-coupling of allenes with primary alcohols via transfer hydrogenation
5.Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hyd rogenation.
6.Useful ligand for iridium- catalyzed C-C cross coupling of allylic gem dicarboxylates with aldehydes via transfer hydrogenation. Useful ligand for the palladium catalyzed synthesis of chiral allenylsilanes.
7.Ruthenium- catalyzed synthesis of indoles
8.Ruthenium-catalyzed oxidative cyclization .
9Rhodium catalyzed boron arylation.

References Data Source From Pubchem

Iridium-Catalyzed “Reverse” Prenylation of Carboxylic Acids

Publication Name: Science of Synthesis
Publication Date: 2024

Using Copper Catalysts

Publication Name: Science of Synthesis
Publication Date: 2023

Synthesis from Enynes and α-Oxo Aldehydes

Publication Name: Science of Synthesis
Publication Date: 2023

Synthesis of Armchair- and Chiral-Type Belts

Publication Name: Synfacts
Publication Date: 2022-04-20
DOI: 10.1055/s-0041-1738059

Stereoselective cyclohexadienylamine synthesis through rhodium-catalysed [2+2+2] cyclotrimerization

Publication Name: Nature Synthesis
Publication Date: 2022-03-28
DOI: 10.1038/s44160-022-00043-2