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Sku SC15-0043_2_G
US-Strem
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Product Information

Product Name
(S)-(+)-2,2'-Bisdi(3,5-di-t-butyl-4-methoxyphenyl)phosphino-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Brand Name
US-Strem
Product Number
15-0043
CAS
910134-30-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11378383
IUPAC Name
2-2-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphanyl-6-methoxyphenyl-3-methoxyphenyl-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane
InChI Key
JSSIQFXOSWLAGA-UHFFFAOYSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC=CC(=C2C3=C(C=CC=C3P(C4=CC(=C(C(=C4)C(C)(C)C)OC)C(C)(C)C)C5=CC(=C(C(=C5)C(C)(C)C)OC)C(C)(C)C)OC)OC)C6=CC(=C(C(=C6)C(C)(C)C)OC)C(C)(C)C

Description

Technical Notes:
1.Ligand for asymmetric Rh-catalyzed Pausan-Khand reaction .
2.Ligand for enantioselective Rh- catalyzed 3 +2 annulation of aromatic ketimines.
3.Ligand for enantioselective copper-organocatalyzed preparation of cyclopentanes bearing an all-carbon
quaternary stereocenters.
4.Ligand for Cu(l)-catalyzed exo- selective construction of spiro-butyrolactonepyrrolidine via 1 ,3-dipolar cycloaddition of azomethine.
5.Ligand for gold-catalyzed enantioselective intramolecular hydroamination of unactivated alkenes.
6.Ligand for rhodium-catalyzed enantioselective intramolecular c -H silylation for the syntheses of planar-chiral metallocene siloles.
7.Ligand for palladium-catalyzed enantioselective intermolecular carboetherification of dihydrofurans.
8.Copper(I)-catalyzed asymmetric exo-selective 3+ 2 cycloaddition of azomethine ylides with ß-trifluoromethyl ß, ß-disubstituted enones.
9.Ligand for Cu-Catalyzed Asymmetric Conjugate Alkynylation of a,ß-Unsaturated 1,1,1-Trifluoromethyl
Ketones with Terminal Alkynes
10. L igand for Rhodium-Catalyzed Asymmetric N-H Functionalization of Quinazolinones with Allylic Carbonates

References Data Source From Pubchem

Enantioselective Addition of Pyridin-2(1H)-ones to Terminal Allenes

Publication Name: Science of Synthesis
Publication Date: 2023

DKR Hydrogenations

Publication Name: Science of Synthesis
Publication Date: 2022

Racemic α-Substituted Imines

Publication Name: Science of Synthesis
Publication Date: 2022

Gold Catalysis

Publication Name: Science of Synthesis
Publication Date: 2016

Enantioselective Gold-Catalyzed Synthesis of Heterocyclic Compounds

Publication Name: Au-Catalyzed Synthesis and Functionalization of Heterocycles
Publication Date: 2015
DOI: 10.1007/7081_2015_5003