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Sku SC15-0044_100_MG
US-Strem
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Product Information

Product Name
(R)-(+)-2,2'-Bisdi(3,5-di-t-butylphenyl)phosphino-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Brand Name
US-Strem
Product Number
15-0044
CAS
192138-05-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10964351
IUPAC Name
2-2-bis(3,5-ditert-butylphenyl)phosphanyl-6-methoxyphenyl-3-methoxyphenyl-bis(3,5-ditert-butylphenyl)phosphane
InChI Key
PBYRAYONARLAQJ-UHFFFAOYSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1)P(C2=CC=CC(=C2C3=C(C=CC=C3P(C4=CC(=CC(=C4)C(C)(C)C)C(C)(C)C)C5=CC(=CC(=C5)C(C)(C)C)C(C)(C)C)OC)OC)C6=CC(=CC(=C6)C(C)(C)C)C(C)(C)C)C(C)(C)C

Description

Technical Notes:
1.Ligand for the highly enantioselective, rhodium-catalyzed 2 +2+2 cycloaddition of diynes to sulfonimines . 2. Ligand for asymmetric gold-catalyzed lactonizations in water at room temperature .
3. Ligand for Rh- Catalyzed Asymmetric 3+2 Cycloaddition Reactions.
References:
1.J. Am. Chem. Soc., 2013, 135, 4576.
2.Angew. Chem. Int. Ed., 2014, 53, 1 0658. 3Angew. Chem. 2016, 128, 7892 7896.

References Data Source From Pubchem

Functionalization of 1,1-Difluoroalkenes

Publication Name: Science of Synthesis
Publication Date: 2025