Product Name
(R)-(+)-2,2'-Bisdi(3,5-di-t-butylphenyl)phosphino-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Certificate of Analysis (COA)
IUPAC Name
2-2-bis(3,5-ditert-butylphenyl)phosphanyl-6-methoxyphenyl-3-methoxyphenyl-bis(3,5-ditert-butylphenyl)phosphane
InChI Key
PBYRAYONARLAQJ-UHFFFAOYSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1)P(C2=CC=CC(=C2C3=C(C=CC=C3P(C4=CC(=CC(=C4)C(C)(C)C)C(C)(C)C)C5=CC(=CC(=C5)C(C)(C)C)C(C)(C)C)OC)OC)C6=CC(=CC(=C6)C(C)(C)C)C(C)(C)C)C(C)(C)C
Technical Notes:
1.Ligand for the highly enantioselective, rhodium-catalyzed 2 +2+2 cycloaddition of diynes to sulfonimines .
2. Ligand for asymmetric gold-catalyzed lactonizations in water at room temperature .
3. Ligand for Rh- Catalyzed Asymmetric 3+2 Cycloaddition Reactions.
References:
1.J. Am. Chem. Soc., 2013, 135, 4576.
2.Angew. Chem. Int. Ed., 2014, 53, 1 0658.
3Angew. Chem. 2016, 128, 7892 7896.