Product Added to Cart!
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%|15-0157|133545-25-2

(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%

$99.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-0157_100_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Brand Name
US-Strem
Product Number
15-0157
CAS
133545-25-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
22173705
IUPAC Name
2-2-bis(4-methylphenyl)phosphanyl-6-methoxyphenyl-3-methoxyphenyl-bis(4-methylphenyl)phosphane
InChI Key
DTMVLPFJTUJZAY-UHFFFAOYSA-N
SMILES
CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=CC=CC(=C3C4=C(C=CC=C4P(C5=CC=C(C=C5)C)C6=CC=C(C=C6)C)OC)OC

Description

Technical Note：
1.See150042
2. Ru and Ir catalyzed dynamic kinetic res olution for the synthesis of hydroxy, amino acidderivatives
3. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
4.lr catalyzed enantioselective hydrogenation of heteroaromatic compounds .
5. Conjugate addition using 2-heteroaryl titanates and zinc reagents.
6.Enantio- and regios elective heck-type reaction of aryl boronic acids with 2,3 dihydrofuran
7.Rhodium-catalyzed carbonyl Z-dienylation.
8.Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones .
References:
1.Adv. Synth. Catal., 2004, 346, 842.
2.Org. L ett., 2006, 8, 4573.
3.Org. Process Res. Devel., 2001, 5, 438.
4.J. Am. Chem. Soc., 2003, 125, 10536.
5.Org. L ett., 2009, 11, 4200.
6.J .Org. Chem., 2007, 72 , 387 5.
7.J. Am. C hem. Soc., 2006, 128, 1 6040.
8.J. Org. Chem., 2011, 76, 6925.