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(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%|15-0655|150971-43-0

(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%

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Sku SC15-0655_10_G
US-Strem
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Product Information

Product Name
(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Brand Name
US-Strem
Product Number
15-0655
CAS
150971-43-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
15823035
IUPAC Name
2-2-di(propan-2-yl)phosphanyl-6-methoxyphenyl-3-methoxyphenyl-di(propan-2-yl)phosphane
InChI Key
HLLUWVKDDQIKNF-UHFFFAOYSA-N
SMILES
CC(C)P(C1=CC=CC(=C1C2=C(C=CC=C2P(C(C)C)C(C)C)OC)OC)C(C)C

Description

Technical Notes:
1.Direct transformation of terminal alkynes to branched allylic sulfones.
2.Novel palladium-catalyzed intramolecular addition of aryl bromides to aldehydes as a key to the synthesis of 3,3-dimethylchroman-4-ones and 3,3-dimethylchroman-4-ols.
3.Ligand for Rh-Catalyzed Asymmetric Hydroalkynylation of Enamides.
References:
1. J. Am. Chem. Soc., 2014, 136, 16124. 2. Chemistry Select, 2018, 3, 11333.
3.J. Am. Chem. Soc.2018, 140, 506- -514.

References Data Source From Pubchem

Using Iridium Catalysis
Publication Name: Science of Synthesis
Publication Date: 2023

Cu-Catalyzed Conjugate Addition of Grignard Reagents to Thiochromones: An Enantioselective Pathway for Accessing 2-Alkylthiochromanones
Publication Name: Synlett
Publication Date: 2018-08-02
DOI: 10.1055/s-0037-1610225

Phosphine-Catalyzed [3+2] Annulation of Cyanoallenes
Publication Name: Synlett
Publication Date: 2011-06-21
DOI: 10.1055/s-0030-1260804