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Sku SC15-0488_500_MG
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Product Information

Product Name
(R)-(+)-2,2'-Bisdi(3,5-xylyl)phosphino-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Brand Name
US-Strem
Product Number
15-0488
CAS
394248-45-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11227787
IUPAC Name
2-2-bis(3,5-dimethylphenyl)phosphanyl-6-methoxyphenyl-3-methoxyphenyl-bis(3,5-dimethylphenyl)phosphane
InChI Key
IMUHNRWTDUVXOU-UHFFFAOYSA-N
SMILES
CC1=CC(=CC(=C1)P(C2=CC=CC(=C2C3=C(C=CC=C3P(C4=CC(=CC(=C4)C)C)C5=CC(=CC(=C5)C)C)OC)OC)C6=CC(=CC(=C6)C)C)C

Safety Information

Storage Condition
Store at 2-8℃

Description

Technical Note 1.See 15-0042.
2.Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives
3.Ru- catalyzed asymmetric hydrogenation of ketones and alkenes.
4.Enantioselective copper-catalyzed asymmetric hydrosilylation of aryl ketones.
5.Synthesis of chiral 3-substituted indanones via an enantioselective reductive-Heck reaction.
6.Gold(1)- catalyzed enantioselective ring expansion of allenylcyclopropanols.
7.Conjugate addition using 2-heteroaryl titanates and zinc reagents .
References:
1. Adv. Synth. Catal., 2004, 346, 842.
2.Org. L ett., 2006, 8, 4573.
3.Org. Process Res. Devel., 2001, 5, 438.
4.J. Am. Chem. Soc., 2001, 123, 1291
7. 5.J. Org. Chem., 2007, 72, 9253.
6.J. Am. Chem. Soc., 2009, 131, 91 78.
7.Org. L ett., 2009, 11, 4200.

References Data Source From Pubchem

Ion-Pair-Directed meta-Selective C–H Borylation of Aromatic Quaternary Ammonium Salts

Publication Name: Synlett
Publication Date: 2017-02-13
DOI: 10.1055/s-0036-1588709

Reactions from Aryl Halides and Pseudohalides

Publication Name: Science of Synthesis
Publication Date: 2016

Use in Alkene and Alkyne Hydroborations

Publication Name: Science of Synthesis
Publication Date: 2014

Chiral Phosphorus Ligands with Interesting Properties and Practical Applications

Publication Name: Asymmetric Catalysis from a Chinese Perspective
Publication Date: 2011-05-31
DOI: 10.1007/978-3-642-19472-6_2

Chiral and Nonchiral [OsX2(diphosphane)(diamine)] (X: Cl, OCH2CF3) Complexes for Fast Hydrogenation of Carbonyl Compounds

Publication Name: Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Date: 2010-03-08
DOI: 10.1002/chem.200902809