(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%|15-0488|394248-45-4

(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%

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Sku SC15-0488_10_G
US-Strem
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Product Information

Product Name
(R)-(+)-2,2'-Bisdi(3,5-xylyl)phosphino-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Brand Name
US-Strem
Product Number
15-0488
CAS
394248-45-4
Certificate of Analysis (COA)​
COA not found

Application

Technical Note 1.See 15-0042.
2.Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives
3.Ru- catalyzed asymmetric hydrogenation of ketones and alkenes.
4.Enantioselective copper-catalyzed asymmetric hydrosilylation of aryl ketones.
5.Synthesis of chiral 3-substituted indanones via an enantioselective reductive-Heck reaction.
6.Gold(1)- catalyzed enantioselective ring expansion of allenylcyclopropanols.
7.Conjugate addition using 2-heteroaryl titanates and zinc reagents .
References:
1. Adv. Synth. Catal., 2004, 346, 842.
2.Org. L ett., 2006, 8, 4573.
3.Org. Process Res. Devel., 2001, 5, 438.
4.J. Am. Chem. Soc., 2001, 123, 1291
7. 5.J. Org. Chem., 2007, 72, 9253.
6.J. Am. Chem. Soc., 2009, 131, 91 78.
7.Org. L ett., 2009, 11, 4200.