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(S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%|15-0159|927396-01-8

(S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%

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Sku SC15-0159_100_MG
US-Strem
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Product Information

Product Name
(S)-(-)-2,2'-Bisdi(3,4,5-trimethoxyphenyl)phosphino-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Brand Name
US-Strem
Product Number
15-0159
CAS
927396-01-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
21806702
IUPAC Name
2-2-bis(3,4,5-trimethoxyphenyl)phosphanyl-6-methoxyphenyl-3-methoxyphenyl-bis(3,4,5-trimethoxyphenyl)phosphane
InChI Key
JZCMGMXFWZWFRX-UHFFFAOYSA-N
SMILES
COC1=C(C(=CC=C1)P(C2=CC(=C(C(=C2)OC)OC)OC)C3=CC(=C(C(=C3)OC)OC)OC)C4=C(C=CC=C4P(C5=CC(=C(C(=C5)OC)OC)OC)C6=CC(=C(C(=C6)OC)OC)OC)OC

Safety Information

Storage Condition
Store at 2-8℃

Description

Technical Notes:
1.See 15-0042.
2.Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives. 3.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes .
4.Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
5.Conjugate addition using 2-heteroaryl titanates and zinc reagents.
6.Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran.
7.Rhodium-catalyzed carbonyl Z-dienylation.
8.Rhodium-catalyzed asymmetric 1 ,4 addition of arylboronic acids to maleimides and enones.
9. Ligand for Rh-Catalyzed Asymmetric Hydrothiolation of Allenes with Aliphatic Thiols .
10. Ligand for Rh-Catalyzed Asymmetric Conjugate Addition of Arylzinc Chlorides to Thiochromones .

References Data Source From Pubchem

By Reduction of Alkynyl Silyl Ketones
Publication Name: Science of Synthesis
Publication Date: 2022