Product Name
(S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (S)-MeO-BIPHEP
Certificate of Analysis (COA)
IUPAC Name
2-(2-diphenylphosphanyl-6-methoxyphenyl)-3-methoxyphenyl-diphenylphosphane
InChI Key
KRJVQCZJJSUHHO-UHFFFAOYSA-N
SMILES
COC1=C(C(=CC=C1)P(C2=CC=CC=C2)C3=CC=CC=C3)C4=C(C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)OC
Technical Note：
1. See 15-0042.
2.Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives .
3.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
4. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
5.Conjugate addition using 2-heteroaryl titanates and zinc reagents.
6.Enantio- and regiose lective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran Rhodium-catalyzed carboncyl Z-dienylation.
References:
1.Adv. Synth. Catal., 2004, 346, 842.
2.Org. L ett., 2006, 8, 4573.
3.Org. Process Res. Devel., 2001, 5, 438
4. J. Am. Chem. Soc., 2003, 125, 10536.
5.Org. L ett., 2009, 1 1, 4200.
6.J. Org. Chem. 2007, 72 , 3875.
7. J. Am. Chem. Soc. 2006, 128, 16040.
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