(R)-4,12-Bis(4-methoxyphenyl)-[2.2]-paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%|45-0255|1038932-68-1

(R)-4,12-Bis(4-methoxyphenyl)-[2.2]-paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%

$521.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC45-0255_500_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(R)-4,12-Bis(4-methoxyphenyl)-2.2-paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
Brand Name
US-Strem
Product Number
45-0255
CAS
1038932-68-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
73995177
IUPAC Name
11-bis(4-methoxyphenyl)phosphanyl-5-tricyclo8.2.2.24,7hexadeca-1(12),4,6,10,13,15-hexaenyl-bis(4-methoxyphenyl)phosphane;(1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate
InChI Key
OTNDHXHQSLLSTC-ONEVTFJLSA-N
SMILES
B-(F)(F)(F)F.COC1=CC=C(C=C1)P(C2=C3C=CC(=C2)CCC4=C(C=C(C=C4)CC3)P(C5=CC=C(C=C5)OC)C6=CC=C(C=C6)OC)C7=CC=C(C=C7)OC.C1/C=C\CC/C=C\C1.Rh

Application

Technical Notes:
1. Highly reactive enantioselective catalyst for the asymmetric hyd rogenation of various substituted dehydroalanines to N-protected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone .
2.Efficient catalyst for the asymmetric reduction of enol acetates to esters.
3.Catalyst used to prepare chiral 2-substituted succinic acid derivatives.
References:
1.J.D. Morrison, Ed., Asymmetric Synthesis (Academic Press, New York, 1985), Vol. 5, 71.
2.Tetrahedron: Asymmetry, 1992. 3, 1247.
3.J.R. Kosak and T.A. Johnson, Eds., Chem Ind. (Marcel Dekker, Inc., New York, 1994) Vol. 53, 81.