Dichloro[(S)-(+)-4,12-bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 95%|44-0381|364795-64-2

Dichloro[(S)-(+)-4,12-bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 95%

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Product Information

Product Name
Dichloro(S)-(+)-4,12-bis(di(3,5-xylyl)phosphino)-2.2-paracyclophane(1R,2R)-(+)-1,2-diphenylethylenediamineruthenium(II), min. 95%
Brand Name
US-Strem
Product Number
44-0381
CAS
364795-64-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
72982616
IUPAC Name
11-bis(3,5-dimethylphenyl)phosphanyl-5-tricyclo8.2.2.24,7hexadeca-1(12),4,6,10,13,15-hexaenyl-bis(3,5-dimethylphenyl)phosphane;dichlororuthenium;1,2-diphenylethane-1,2-diamine
InChI Key
RNYWYINSJUUIIP-UHFFFAOYSA-L
SMILES
CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=C4CCC5=CC(=C(CCC(=C3)C=C4)C=C5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C.C1=CC=C(C=C1)C(C(C2=CC=CC=C2)N)N.ClRuCl

Application

Technical Notes:
1. The Noyori (diphosphine) RuClz (diamine) catalysts containing the chiral ligand Xylyl-Phanephos display exceptional activity and enantioselectivity in the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic and a,ß-unsaturatedketones.
2.Reactions are performed under mild conditions at room temperature and typically at low Hz pressures of 2-10 bar. substrate concentrations of up to 40% w/v are tolerated
3.Molar substrate/catalyst ratios of up to 1 00,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
References:
1.Org. Lett.. 2000, 2. 4173.
2.Burk, M.J.; Hems. w.; Zanotti-Gerosa, A. PCT WO/0 174829 A1, 2001. 3.Org. Proc. Res. Dev.. 2003, 7, 89.