(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (S)-PHANEPHOS|15-0426|192463-40-4

(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (S)-PHANEPHOS

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Sku SC15-0426_500_MG
US-Strem
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Product Information

Product Name
(S)-(+)-4,12-Bis(diphenylphosphino)-2.2-paracyclophane, min. 95% (S)-PHANEPHOS
Brand Name
US-Strem
Product Number
15-0426
CAS
192463-40-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10864772
IUPAC Name
(11-diphenylphosphanyl-5-tricyclo8.2.2.24,7hexadeca-1(12),4,6,10,13,15-hexaenyl)-diphenylphosphane
InChI Key
GYZZZILPVUYAFJ-UHFFFAOYSA-N
SMILES
C1CC2=C(C=C(CCC3=C(C=C1C=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)C=C2)P(C6=CC=CC=C6)C7=CC=CC=C7

Application

Technical Notes:
1.Ligand for rhodium-catalyzed enantioselective hydroboration of cyclopropenes .
2. Ligand for iridium-catalyzed enantioselective 2 +2 cycloaddition of oxabicyclic alkenes with terminal alkynes.
3.Ligand for the palladium -catalyzed enantioselective hydroxycarbonylation and alkoxycarbonylation ofalkenes
4. Ligand for the palladium- catalyzed amides synthesis via C(sp3)- -H bond functionalization and co insertion.
5. Ligand for iridium-catalyzed diene hydrohydroxym ethylation.

References Data Source From Pubchem

Additions to Aldehydes
Publication Name: Science of Synthesis
Publication Date: 2022

Circularly polarised luminescence from planar-chiral Phanephos/Tb(III)(hfa)3 hybrid luminophores
Publication Name: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
Publication Date: 2019-12-01
DOI: 10.1039/c9pp00296k

Transition-Metal-Catalyzed Asymmetric Allylation of Carbonyl Compounds with Unsaturated Hydrocarbons
Publication Name: Synthesis
Publication Date: 2017-12-21
DOI: 10.1055/s-0036-1590986

Enantioselective Iridium-Catalyzed Hydro-hydroxymethylation of Trifluoromethyl Allenes
Publication Name: Synfacts
Publication Date: 2017-08-18
DOI: 10.1055/s-0036-1591174

Luminescent Cationic Copper(I) Complexes: Synthesis, Photophysical Properties and Application in Light-Emitting Electrochemical Cells
Publication Name: Light-Emitting Electrochemical Cells
Publication Date: 2017
DOI: 10.1007/978-3-319-58613-7_11