(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(S)-3,5-xylyl-PHANEPHOS|15-0731|325168-88-5

(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 95% CTH-(S)-3,5-xylyl-PHANEPHOS

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Sku SC15-0731_500_MG
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Product Information

Product Name
(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-2.2-paracyclophane, min. 95% CTH-(S)-3,5-xylyl-PHANEPHOS
Brand Name
US-Strem
Product Number
15-0731
CAS
325168-88-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11263179
IUPAC Name
11-bis(3,5-dimethylphenyl)phosphanyl-5-tricyclo8.2.2.24,7hexadeca-1(12),4,6,10,13,15-hexaenyl-bis(3,5-dimethylphenyl)phosphane
InChI Key
LYHOBZAADXPPNW-UHFFFAOYSA-N
SMILES
CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=C4CCC5=CC(=C(CCC(=C3)C=C4)C=C5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C

Application

Technical Notes:
1.See 15-0426
2.Chiral ligand employed in the enantioselective hydrogenation of various ketones.
3.Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
4.Chiral ligand employed in the enantioselective 2 +2 cycloaddition of oxa bicyclic alkenes with terminal alkynes. 5.Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.
References:
1.Org. L ett., 2000, 2, 4173.
2.Angew. Chem. Int. Ed., 2010, 49, 9197.
3.Org. L ett., 2010, 12, 304.
4Nature Chemistry, 2012, 4, 405.

References Data Source From Pubchem

Racemic α-Alkyl/Aryl-Substituted Ketones
Publication Name: Science of Synthesis
Publication Date: 2022

Chiral Iridium Catalysts
Publication Name: Science of Synthesis
Publication Date: 2011

Kinetic Resolution of Racemates Using Enantiopure Phosphines
Publication Name: Science of Synthesis
Publication Date: 2009

Ruthenium-Promoted Hydrogenation of Ketones
Publication Name: Science of Synthesis
Publication Date: 2009