(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS|15-0425|364732-88-7

(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS

$138.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-0425_100_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(R)-(-)-4,12-Bis(diphenylphosphino)-2.2-paracyclophane, min. 95% (R)-PHANEPHOS
Brand Name
US-Strem
Product Number
15-0425
CAS
364732-88-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10864772
IUPAC Name
(11-diphenylphosphanyl-5-tricyclo8.2.2.24,7hexadeca-1(12),4,6,10,13,15-hexaenyl)-diphenylphosphane
InChI Key
GYZZZILPVUYAFJ-UHFFFAOYSA-N
SMILES
C1CC2=C(C=C(CCC3=C(C=C1C=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)C=C2)P(C6=CC=CC=C6)C7=CC=CC=C7

Application

Technical Notes:
1.Catalyst for the hydroxyl-directed epoxidation of olefins. 2. Catalyst for the asymmetric oxidation of disulfides.
3. Catalyst for the Mannich reaction.
4. Catalyst for sulfoxidation of alkanes.
References:

1. Chem. Rev., 1993, 93, 1307.
2.Org. L ett., 2009, 1 1, 2896.
3.J. Am. Chem. Soc., 1998, 120, 801 1.
4.Org. L ett., 2002, 4, 463.
5.Chem.Comm.,009,3169.
6.J. Am. ( hem. Soc., 2000, 122, 7390.
7.J. Am. ( hem. Soc., 2001, 123, 1 545.

References Data Source From Pubchem

Additions to Aldehydes
Publication Name: Science of Synthesis
Publication Date: 2022

Circularly polarised luminescence from planar-chiral Phanephos/Tb(III)(hfa)3 hybrid luminophores
Publication Name: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
Publication Date: 2019-12-01
DOI: 10.1039/c9pp00296k

Transition-Metal-Catalyzed Asymmetric Allylation of Carbonyl Compounds with Unsaturated Hydrocarbons
Publication Name: Synthesis
Publication Date: 2017-12-21
DOI: 10.1055/s-0036-1590986

Enantioselective Iridium-Catalyzed Hydro-hydroxymethylation of Trifluoromethyl Allenes
Publication Name: Synfacts
Publication Date: 2017-08-18
DOI: 10.1055/s-0036-1591174

Luminescent Cationic Copper(I) Complexes: Synthesis, Photophysical Properties and Application in Light-Emitting Electrochemical Cells
Publication Name: Light-Emitting Electrochemical Cells
Publication Date: 2017
DOI: 10.1007/978-3-319-58613-7_11