Organometallic chemistry is a dynamic field that explores the synthesis, structure, reactivity, properties, and applications of metal-organic compounds. These compounds, formed by a central metal atom bonded to surrounding organic ligands, play a vital role in advancing modern science and technology.

Among the most innovative developments in this field are Carbolong Complexes—a class of compounds featuring a planar conjugated carbon chain (with seven or more carbon atoms) connected through at least three carbon-metal bonds. These complexes are formed by bonding transition metals to extended carbon frameworks.

In 2013, Professor Xia Haiping’s research group pioneered the synthesis and naming of Carbolong Complexes. Their work led to the creation of a series of original structures with exceptional performance characteristics. These complexes exhibit high reactivity and can be tailored through pre-modification and post-derivatization, enabling the development of diverse functional molecules.

Applications of Carbolong Complexes span multiple cutting-edge fields, including:

  • Light energy conversion
  • Biomedicine
  • Homogeneous catalysis
  • Oxygen activation

J&K Scientific: Exclusive Provider of Carbon Dragon Complexes

J&K Scientific is proud to exclusively offer select carbonium complexes developed by Professor Xia Haiping’s team. In addition, we provide a comprehensive range of supporting products for metal-organic chemistry research:

  • Complete Product Range: Covering three major categories—metal catalysts, metal precursors for synthesis, and ligands. We also supply commonly used organometallic reagents, synthesis reagents, ultra-dry solvents, NMR solvents, and essential laboratory consumables.

  • Frontier Products: Access to newly developed metal-organic complexes and synthetic reagents derived directly from the latest scientific research by leading experts in the field.

  • Quality Assurance: Our products are characterized by high purity, rigorous quality control, and consistent batch stability.

 

Recommended products

Product name CAS Item number
8C Carbolong complex, 95% 1667743-98-7 9307661
12C Carbolong complex, 95% 2917610-83-2 9307662
Carbolong peroxo complex, 95% 2244156-01-0 9307663
Os-Cu Carbolong complex, 95% 2225872-98-8 9307664
Phenanthroline-Carbolong, 95% N/A 9307665

 

Metal Catalyst

Product name CAS Item number
Dichlorobis(triphenylphosphine)palladium(II), 98% 13965-03-2 242195
Dicobalt octacarbonyl, 95% 10210-68-1 533379
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-3-chloropyridine complex, 98% 1349182-65-5 9187355

 

Metal Precursor

Product name CAS Item number
Titanium(IV) chloride, 1 M solution in dichloromethane, J&KSeal 7550-45-0 459124
Vanadium(V) oxide, 99%, for synthesis 1314-62-1 972308
Zinc chloride, 98%, for analysis 7646-85-7 975486

 

Ligand

Product name CAS Item number
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98% (S,S)-Ph-BPE 824395-67-7 15-0474
(4R,5R)-(-)-2,2-Dimethyl-4,5-bis((diphenylphosphino)methyl)-1,3-dioxolane, 98% 32305-98-9 453464
Triphenylphosphine, 99%, Cl:≤30 ppm 603-35-0 993263

 

Azo and Diazo

Product name CAS Item number
Ethyl diazoacetoacetate, 98% 2009-97-4 460520
Ethyl diazoacetate, 95% 623-73-4 282677

 

Molecular Building Blocks

Product name CAS Item number
Glycolic acid, 99% 79-14-1 147016
3-Pentyn-1-ol, 98% 10229-10-4 571781
3-Phenyl-1-propyne, 97%, stabilized 10147-11-2 235212

 

Organometallic Reagents

Product name CAS Item number
3,5-Dimethylphenylmagnesium bromide, 0.5 M solution in THF 34696-73-6 911858
n-Butyllithium, 1.6 M solution in hexanes, J&KSeal 109-72-8 274232
Vinylmagnesium bromide, 1.0 M solution in THF, J&KSeal 1826-67-1 309166

 

Synthetic Reagents

Product name CAS Item number
Potassium tert-butoxide, 1.0 M solution in THF, J&KSeal 865-47-4 962820
Titanium(IV) isopropoxide, 98% 546-68-9 162947
1,5,7-Triazabicyclo[4.4.0]dec-5-ene, 98% 5807-14-7 478441

 

General Product

Product name CAS Item number
Potassium carbonate, 99% 584-08-7 212583
Sodium sulfate, 99%, anhydrous, for residue analysis 7757-82-6 940131
Dimethyl sulfoxide-d6, N/A, 99.8 atom%D, contains 0.03% v/v TMS 2206-27-1 182473
By 向阳 翟

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