Organometallic chemistry plays a crucial role in the development of modern chemical synthesis, focusing on the synthesis, structure, reactions, properties, and applications of metal-organic compounds. These compounds, consisting of a central metal atom and surrounding ligands, are widely used as catalysts in organic synthesis, particularly in transition metal-catalyzed reactions.

Professor Tu Tao

Professor Tu Tao from Fudan University has developed three novel nitrogen heterocyclic carbene (NHC) metal catalysts based on acenaphthyl, di- and triazacarbene ligands. These Ir, Pd, and Au-based catalysts exhibit excellent catalytic activity and selectivity in key organic transformations, including:

  • Oxidative dehydrogenation of alcohols
  • Sulfonylation reactions
  • Reductive amination with sulfur dioxide insertion

These breakthroughs offer new possibilities for efficient and selective catalysis in synthetic chemistry.


J&K Scientific exclusively provides the scientific research results of Professor Tu Tao - new nitrogen heterocyclic carbene metal catalysts, and can also provide a variety of metal-organic chemistry supporting products:

  • Complete range: covering three major series: metal catalysts, metal precursors for synthesis, and ligands, commonly used organometallic reagents, synthesis reagents, ultra-dry solvents, nuclear magnetic solvents and commonly used instrument consumables;
  • Product frontier: We can provide new metal-organic complexes and synthetic reagents that are transformed from the scientific research results of experts and scholars in this field;
  • Quality assurance: high purity, strict quality control, and stable batch quality.

Recommended products

Product name CAS Item number
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-benzyldiethylamine complex, 98% 2127163-68-0 9187352
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-3-chloropyridine complex, 98% 1349182-65-5 9187355
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-allyl complex, 98% 1446132-83-7 9187358
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-allyl-phenyl complex, 98% 2152683-05-9 9187369

 

Metal precursor

Product name CAS Item number
Iridium(III) chloride hydrate, 50 - 58% Ir 14996-61-3 110534
Iron(II) chloride tetrahydrate, 99% 13478-10-9 93-2632
Iron(III) acetylacetonate, 98% 14024-18-1 165348

 

Ligand

Product name CAS Item number
(4R,5R)-(-)-2,2-Dimethyl-4,5-bis((diphenylphosphino)methyl)-1,3-dioxolane, 98% 32305-98-9 453464
Tricyclohexylphosphine, 97% 2622-14-2 128983
Triphenylphosphine, 99%, Cl:≤30 ppm 603-35-0 993263

 

Azo and Diazo

Product name CAS Item number
Ethyl diazoacetoacetate, 98% 2009-97-4 460520
Ethyl diazoacetate, 95% 623-73-4 282677

 

Molecular building blocks

Product name CAS Item number
3-Phenyl-1-propyne, 97%, stabilized 10147-11-2 235212
3-Pentyn-1-ol, 98% 10229-10-4 571781
Pyridine, 99%, ACS reagent 110-86-1 939435

 

Organometallic reagents

Product name CAS Item number
3,5-Dimethylphenylmagnesium bromide, 0.5 M solution in THF 34696-73-6 911858
2-Mesitylmagnesium bromide, 1.0 M solution in THF, J&KSeal 2633-66-1 914974
2-Methyl-1-propenylmagnesium bromide, 0.5 M solution in THF, J&KSeal 38614-36-7 611972

 

Synthetic reagents

Product name CAS Item number
Diisobutylaluminum hydride, 1.0 M solution in hexanes, J&Kseal, Colorless 1191-15-7 997665
Dimethylphenylsilane, 97% 766-77-8 142316
Iodomethane, 99%, stabilized with copper chip 74-88-4 395069

 

General product

Product name CAS Item number
Ethyl acetate, 99.5%, SuperDry, J&KSeal 141-78-6 954403
n-Hexane, 95%, for residue analysis, water: ≤0.01% 110-54-3 932563
Methanol-d4, N/A, 99.8 atom%D 811-98-3 114655

 

By 向阳 翟

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