Organometallic chemistry plays a crucial role in the development of modern chemical synthesis, focusing on the synthesis, structure, reactions, properties, and applications of metal-organic compounds. These compounds, consisting of a central metal atom and surrounding ligands, are widely used as catalysts in organic synthesis, particularly in transition metal-catalyzed reactions.

Professor Tu Tao from Fudan University has developed three novel nitrogen heterocyclic carbene (NHC) metal catalysts based on acenaphthyl, di- and triazacarbene ligands. These Ir, Pd, and Au-based catalysts exhibit excellent catalytic activity and selectivity in key organic transformations, including:
- Oxidative dehydrogenation of alcohols
- Sulfonylation reactions
- Reductive amination with sulfur dioxide insertion
These breakthroughs offer new possibilities for efficient and selective catalysis in synthetic chemistry.
J&K Scientific exclusively provides the scientific research results of Professor Tu Tao - new nitrogen heterocyclic carbene metal catalysts, and can also provide a variety of metal-organic chemistry supporting products:
- Complete range: covering three major series: metal catalysts, metal precursors for synthesis, and ligands, commonly used organometallic reagents, synthesis reagents, ultra-dry solvents, nuclear magnetic solvents and commonly used instrument consumables;
- Product frontier: We can provide new metal-organic complexes and synthetic reagents that are transformed from the scientific research results of experts and scholars in this field;
- Quality assurance: high purity, strict quality control, and stable batch quality.
Recommended products
Product name | CAS | Item number |
---|---|---|
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-benzyldiethylamine complex, 98% | 2127163-68-0 | 9187352 |
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-3-chloropyridine complex, 98% | 1349182-65-5 | 9187355 |
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-allyl complex, 98% | 1446132-83-7 | 9187358 |
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-allyl-phenyl complex, 98% | 2152683-05-9 | 9187369 |
Metal precursor
Product name | CAS | Item number |
---|---|---|
Iridium(III) chloride hydrate, 50 - 58% Ir | 14996-61-3 | 110534 |
Iron(II) chloride tetrahydrate, 99% | 13478-10-9 | 93-2632 |
Iron(III) acetylacetonate, 98% | 14024-18-1 | 165348 |
Ligand
Product name | CAS | Item number |
---|---|---|
(4R,5R)-(-)-2,2-Dimethyl-4,5-bis((diphenylphosphino)methyl)-1,3-dioxolane, 98% | 32305-98-9 | 453464 |
Tricyclohexylphosphine, 97% | 2622-14-2 | 128983 |
Triphenylphosphine, 99%, Cl:≤30 ppm | 603-35-0 | 993263 |
Azo and Diazo
Product name | CAS | Item number |
---|---|---|
Ethyl diazoacetoacetate, 98% | 2009-97-4 | 460520 |
Ethyl diazoacetate, 95% | 623-73-4 | 282677 |
Molecular building blocks
Product name | CAS | Item number |
---|---|---|
3-Phenyl-1-propyne, 97%, stabilized | 10147-11-2 | 235212 |
3-Pentyn-1-ol, 98% | 10229-10-4 | 571781 |
Pyridine, 99%, ACS reagent | 110-86-1 | 939435 |
Organometallic reagents
Product name | CAS | Item number |
---|---|---|
3,5-Dimethylphenylmagnesium bromide, 0.5 M solution in THF | 34696-73-6 | 911858 |
2-Mesitylmagnesium bromide, 1.0 M solution in THF, J&KSeal | 2633-66-1 | 914974 |
2-Methyl-1-propenylmagnesium bromide, 0.5 M solution in THF, J&KSeal | 38614-36-7 | 611972 |
Synthetic reagents
Product name | CAS | Item number |
---|---|---|
Diisobutylaluminum hydride, 1.0 M solution in hexanes, J&Kseal, Colorless | 1191-15-7 | 997665 |
Dimethylphenylsilane, 97% | 766-77-8 | 142316 |
Iodomethane, 99%, stabilized with copper chip | 74-88-4 | 395069 |
General product
Product name | CAS | Item number |
---|---|---|
Ethyl acetate, 99.5%, SuperDry, J&KSeal | 141-78-6 | 954403 |
n-Hexane, 95%, for residue analysis, water: ≤0.01% | 110-54-3 | 932563 |
Methanol-d4, N/A, 99.8 atom%D | 811-98-3 | 114655 |