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(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh|45-0184|521272-85-5

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh

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Sku SC45-0184_500_MG
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Product Information

Product Name
(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo2.2.1hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh
Brand Name
US-Strem
Product Number
45-0184
CAS
521272-85-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
12690484
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;(3-diphenylphosphanyl-2-bicyclo2.2.1hept-5-enyl)-diphenylphosphane;rhodium;tetrafluoroborate
InChI Key
DPXNIIPVFLWYAU-ONEVTFJLSA-N
SMILES
B-(F)(F)(F)F.C1/C=C\CC/C=C\C1.C1C2C(C(C1C=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6.Rh

Description

Technical Notes:
1. L igand used in the enantioselective rhodium catalyzed hydrogenation of a dehydroaminoesters and enamides. 2. L igand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
3. L igand used in the asymmetric rhodium catalyzed cleavage of racemic 1 ,3-oxazolidines.
References:
1. Angew. Chem., 1979, 91, 655.
2. J. Am. Chem. Soc.. 2003, 125, 7198. 3. Adv. Synth. Catal. 2003, 345, 239.