Product Added to Cart!
(2R,3R)-(-)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95% (R,R)-NORPHOS|15-0140|71042-55-2

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95% (R,R)-NORPHOS

$549.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-0140_1_G
US-Strem
Get Bulk Quote

Product Information

Product Name
(2R,3R)-(-)-2,3-Bis(diphenylphosphino)-bicyclo2.2.1hept-5-ene, min. 95% (R,R)-NORPHOS
Brand Name
US-Strem
Product Number
15-0140
CAS
71042-55-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
12681292
IUPAC Name
(2R,3R)-3-diphenylphosphanyl-2-bicyclo2.2.1hept-5-enyl-diphenylphosphane
InChI Key
CDJHPMXMJUCLPA-YRNSEASESA-N
SMILES
C1C2C=CC1C@H(C@@H2P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6

Description

Technical Notes:
1.Ligand used in the enantioselective rhodium catalyzed hydrogenation of a dehydroaminoesters and enamides.
2. L igand used in the enantios elective rhodium catalyzed hydroboration of cyclopropenes.
3. L igand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
4. Iridium or Rhodium-catalyzed asymmetric Diels-Alder reaction.
References:
1.Angew. Chem. 1979, 91, 655.
2. J. Ăm. Chem. Soc.. 2003, 125, 7198. 3. Adv. Synth. Catal., 2003, 345, 239. 4. Organometallics, 2011, 30, 6661 .

References Data Source From Pubchem

An Investigation of the Asymmetric Huisgen ‘Click’ Reaction1
Publication Name: Synlett
Publication Date: 2013-11-05
DOI: 10.1055/s-0033-1340152

Synthesis of Cationic Chiral Diene Complexes
Publication Name: Science of Synthesis
Publication Date: 2001

Enantioselective Catalysis with Transition Metal Complexes
Publication Name: Chemical Synthesis
Publication Date: 1996
DOI: 10.1007/978-94-009-0255-8_7

Enantioselective Synthesis of Organic Compounds with Optically Active Transition Metal Catalysts and Transition Metal Compounds
Publication Name: Organometallics in Organic Synthesis 2
Publication Date: 1989
DOI: 10.1007/978-3-642-74269-9_15

Neue Geräte und Chemikalien
Publication Name: Fresenius' Zeitschrift für analytische Chemie
Publication Date: 1985
DOI: 10.1007/bf00497203