(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh|45-0185|78355-59-6

(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh

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Product Information

Product Name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo2.2.1hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh
Brand Name
US-Strem
Product Number
45-0185
CAS
78355-59-6
Certificate of Analysis (COA)​
COA not found

Application

Technical Notes:
1. L igand used in the enantioselective rhodium catalyzed hydrogenation of a dehydroaminoesters and enamides. 2. L igand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
3. L igand used in the asymmetric rhodium catalyzed cleavage of racemic 1 ,3-oxazolidines.
References:
1. Angew. Chem., 1979, 91, 655.
2. J. Am. Chem. Soc.. 2003, 125, 7198. 3. Adv. Synth. Catal. 2003, 345, 239.