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(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95% (S,S)-NORPHOS|15-0141|71042-54-1

(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95% (S,S)-NORPHOS

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Sku SC15-0141_250_MG
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Product Information

Product Name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo2.2.1hept-5-ene, min. 95% (S,S)-NORPHOS
Brand Name
US-Strem
Product Number
15-0141
CAS
71042-54-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10183166
IUPAC Name
(1R,2S,3S,4S)-3-diphenylphosphanyl-2-bicyclo2.2.1hept-5-enyl-diphenylphosphane
InChI Key
CDJHPMXMJUCLPA-QHNMYUOLSA-N
SMILES
C1C@@H2C=CC@H1C@@H(C@H2P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6

Description

Technical Notes:
1. L igand used in the enantioselective rhodium catalyzed hydrogenation of a -dehydroaminoesters and enamides . 2.Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
3. L igand used in the asymmetric rhodium catalyzed cleavage of racemic 1 ,3-oxazolidines.
References:
1. Angew. Chem., 1979, 91, 655.
2. J. Am. Chem. Soc. 2003, 125, 7198.
3. Adv. Synth. Catal. 2003, 345, 239.

References Data Source From Pubchem

The highly surprising behaviour of diphosphine ligands in iron-catalysed Negishi cross-coupling
Publication Name: Nature Catalysis
Publication Date: 2018-12-31
DOI: 10.1038/s41929-018-0197-z

Confinement effect of rhodium(I) complex species on mesoporous MCM-41 and SBA-15: effect of pore size on the hydroformylation of 1-octene
Publication Name: Journal of Porous Materials
Publication Date: 2017-05-30
DOI: 10.1007/s10934-017-0443-9

1,2- Versus 1,4-Asymmetric Reduction of Ketones
Publication Name: Progress in Enantioselective Cu(I)-catalyzed Formation of Stereogenic Centers
Publication Date: 2015
DOI: 10.1007/3418_2015_157

Gas-Chromatographic Enantioseparation of Unfunctionalized Chiral Hydrocarbons: An Overview
Publication Name: Methods in molecular biology (Clifton, N.J.)
Publication Date: 2013
DOI: 10.1007/978-1-62703-263-6_3

Asymmetric Reductive Amination
Publication Name: Stereoselective Formation of Amines
Publication Date: 2013
DOI: 10.1007/128_2013_484