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Sku SC15-8559_100_MG
US-Strem
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Product Information

Product Name
(6aS)-14-Hydroxy-6,7-diphenyl-14-oxide-dinaphtho1,2-d:2',1'-f1,3,2dioxaphosphepin, 98%, (99% ee)
Brand Name
US-Strem
Product Number
15-8559
CAS
175223-61-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
15258684
IUPAC Name
13-hydroxy-3,23-diphenyl-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.05,10.016,21tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
InChI Key
MJERWFPNPBWGNM-UHFFFAOYSA-N
SMILES
C1=CC=C(C=C1)C2=CC3=CC=CC=C3C4=C2C5=C(C6=CC=CC=C6C=C5C7=CC=CC=C7)OP(=O)(O4)O

Application

Technical Notes:
1. Used in the enantioselective racemic resolution of a range of 1 ,2-amino via liquid-liquid extraction ofalcohols.
References:
1. ChemSusChem 2018, 11, 178.

References

New Derivatives of VAPOL and VANOL: Structurally Distinct Vaulted Chiral Ligands and Brønsted Acid Catalysts

Publication Name: Synthesis
Publication Date: 2010-08-25
DOI: 10.1055/s-0030-1258231