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Sku SC07-0417_250_MG
US-Strem
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Product Information

Product Name
6,7-Dihydro-2-pentafluorophenyl-5H-pyrrolo2,1-c-1,2,4-triazolium tetrafluoroborate, min. 98%
Brand Name
US-Strem
Product Number
07-0417
CAS
862095-91-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11152694
IUPAC Name
2-(2,3,4,5,6-pentafluorophenyl)-6,7-dihydro-5H-pyrrolo2,1-c1,2,4triazol-4-ium tetrafluoroborate
InChI Key
KIWCIWCCQVTPOY-UHFFFAOYSA-N
SMILES
B-(F)(F)(F)F.C1CC2=NN(C=N+2C1)C3=C(C(=C(C(=C3F)F)F)F)F

Description

Technical Notes:
1. Reagent used in the highly enantio- and diastereoselective, catalytic intramolecular Stetter reaction.
2. Enantioselective synthesis of ß-hydroxy and ß-amino esters.
3.Organocatalytic iminium ion/carbene reaction cascade for the formation of 2,4-disubstituted cyclopentenones . 4. Synthesis of allo- and epi-lnositol via the NHC-catalyzed carbocyclization of carbohydrate-derived dialdehydes.
References:
1.J. Org. Chem., 2008,73, 2033.
2.J. Am. Chem. Soc., 2006, 128, 2552.
3.Org. L ett., 2008, 10, 3141.
4.Org. L ett., 201 o, 12, 5052.
5.Org. Lett., 2011, 13, 4790.
6. J. Org. Chem., 2014,79, 5088.

References Data Source From Pubchem

Using α,β-Unsaturated Aldehydes

Publication Name: Science of Synthesis
Publication Date: 2024

Synthesis from Aldehydes

Publication Name: Science of Synthesis
Publication Date: 2024

Application to Natural Product Synthesis

Publication Name: Science of Synthesis
Publication Date: 2012

N-Heterocyclic Carbene Catalyzed Ring-Expansion Reactions of Other Heterocycles

Publication Name: Science of Synthesis
Publication Date: 2012

N-Heterocyclic Carbene Catalyzed Redox Amidations

Publication Name: Science of Synthesis
Publication Date: 2012