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Sku SC07-0414_500_MG
US-Strem
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Product Information

Product Name
(5aS,10bR)-(-)-5a,10b-Dihydro-2-(pentafluorophenyl)-4H,6H-indeno2,1-b1,2,4trizolo4,3-d1,4oxazinium tetrafluoroborate (contains 15-20% minor isomer)
Brand Name
US-Strem
Product Number
07-0414
CAS
740816-14-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11190533
IUPAC Name
(1R,9S)-4-(2,3,4,5,6-pentafluorophenyl)-8-oxa-4,5-diaza-2-azoniatetracyclo7.7.0.02,6.011,16hexadeca-2,5,11,13,15-pentaene tetrafluoroborate
InChI Key
CPCMDOOTVHDRTM-OUYNRQGDSA-N
SMILES
B-(F)(F)(F)F.C1C@H2C@@H(C3=CC=CC=C31)N+4=CN(N=C4CO2)C5=C(C(=C(C(=C5F)F)F)F)F

Description

Technical Notes:
1.Used in triazolium-catalyzed carbocyclization of carbohydrate - derived dialdehydes to produce allo- and epi-inositol.
2.Triazolium catalyst for enantioselective Darzens reactions.
3.Catalyst for L ewis acid assisted reaction of 2-aroylvinylcinnamaldehydes to produce indeno-1 ,2-cfuran-1- one derivatives.
4.Catalyst for asymmetric desymmetrization of 1 ,3-Diketones via Intramolecular benzoin reaction.
5.Catalyst for asymmetric synthesis of spirobenzazepinones with atroposelectivity and spiro-1,2-diazepinones by 3+4 annulation reactions.
6.Catalysis for a highly enantioselective 4+2 annulation.

References Data Source From Pubchem

Reaction Using an Electron-Deficient Arylhydrazine

Publication Name: Science of Synthesis
Publication Date: 2012