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(11bS)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepinium bromide|07-0381|851942-89-7

(11bS)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepinium bromide

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Sku SC07-0381_50_MG
US-Strem
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Product Information

Product Name
(11bS)-4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho2,1-c:1',2'-eazepinium bromide
Brand Name
US-Strem
Product Number
07-0381
CAS
851942-89-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11445600
IUPAC Name
13,13-dibutyl-10,16-bis(3,4,5-trifluorophenyl)-13-azoniapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene bromide
InChI Key
LOMUZNOWQYZTRP-UHFFFAOYSA-M
SMILES
CCCCN+1(CC2=C(C3=CC=CC=C3C=C2C4=CC(=C(C(=C4)F)F)F)C5=C(C1)C(=CC6=CC=CC=C65)C7=CC(=C(C(=C7)F)F)F)CCCC.Br-

Description

Technical Notes:
1.2nd Generation Maruoka chiral phase transfer catalyst, for enantios elective alkylation of a-amino acid derivatives, that is easily recycled by extraction with fluorous solvent.
2.Catalyst for asymmetric conjugate addition of a-substituted-a-cyanoacetates to a,ß-unsaturated acetylenic esters .
3.Phase transfer catalyzed enantioselective a-alkylation.
4.Asymmetric amination of ß-keto esters.
5.Diastereo- and enantioselective conjugate addition of a-substituted nitroacetates to maleimides .
6.Efficient asymmetric synthesis of spiro-2(3H)-furanones via phase-transfer-catalyzed alkynylation.
7.Phase-transfer catalyzed asymmetric synthesis of a,ß-unsaturated v,y-disubstituted y-lactams.

References Data Source From Pubchem

Enantioselective Synthesis of Carbon-11-Labeled Amino Acids and Peptides
Publication Name: Methods in molecular biology (Clifton, N.J.)
Publication Date: 2024
DOI: 10.1007/978-1-0716-3499-8_2

α-Arylation of Alkyl Alkanoates with Aryl Halides
Publication Name: Science of Synthesis
Publication Date: 2024

Catalytic enantioselective synthesis of atropisomeric biaryls by a cation-directed O-alkylation.
Publication Name: Nature Chemistry
Publication Date: 2017-01-23
DOI: 10.1038/nchem.2710

Catalytic enantioselective synthesis of indanes by a cation-directed 5-endo-trig cyclization.
Publication Name: Nature Chemistry
Publication Date: 2015-01-12
DOI: 10.1038/nchem.2150

Phase-transfer catalysed asymmetric synthesis of tetrasubstituted allenes.
Publication Name: Nature Chemistry
Publication Date: 2013-02-10
DOI: 10.1038/nchem.1567