(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (S)-ShiP|15-5157|885701-71-3

(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (S)-ShiP

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Sku SC15-5157_500_MG
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Product Information

Product Name
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno7,1-de:1',7'-fg1,3,2dioxaphosphocin-5-phenoxy, min. 98% (S)-ShiP
Brand Name
US-Strem
Product Number
15-5157
CAS
885701-71-3
Certificate of Analysis (COA)​
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Application

Technical Notes:
1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
2.Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids
3.Chiral ligands for rhodium-catalyzed arylation of a-ketoesters with arylboronic acids. 4.Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes .
5.Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-ß-arylenamides.
References:
1.Org. Lett. 2006, 8, 1479.
2.Org. Lett. 2006, 8, 2567 .
3.Angew. Chem. Int. Ed. 2008, 47, 4351. 4.Chem. Sci. 2011, 2, 1135.
5.Tetrahedron 2012, 68, 7685.