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Sku SC15-1521_100_MG
US-Strem
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Product Information

Product Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta2,1-a;3,4-a'dinaphthalen-4-yl)bis(1S)-1-phenylethylamine, min. 95%
Brand Name
US-Strem
Product Number
15-1521
CAS
380230-02-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11731247
IUPAC Name
N,N-bis(1S)-1-phenylethyl-12,14-dioxa-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine
InChI Key
LKZPDRCMCSBQFN-UIOOFZCWSA-N
SMILES
CC@@H(C1=CC=CC=C1)N(C@@H(C)C2=CC=CC=C2)P3OC4=C(C5=CC=CC=C5C=C4)C6=C(O3)C=CC7=CC=CC=C76

Application

Technical Notes:
1.A ligand for asymmetric conjugate addition of dialkyI zinc reagents to activated olefins.
2.Iridium-catalyzed regioselective and enantioselective allylation of enamines.
3.Iridium-catalyzed asymmetric allylation of KSAc.
References:
1.Org. Lett., 2002, 4, 3835.
2. J. Am. Chem. Soc., 2007, 129, 7720. 3.Eur. J. Org. Chem., 2013, 2708.

References Data Source From Pubchem