(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%|15-1510|490023-37-5

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%

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Sku SC15-1510_500_MG
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Product Information

Product Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta2,1-a;3,4-a'dinaphthalen-4-yl)benzyl(methyl)amine, 99%
Brand Name
US-Strem
Product Number
15-1510
CAS
490023-37-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11453323
IUPAC Name
N-benzyl-N-methyl-12,14-dioxa-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine
InChI Key
OHGGHRJGBXAKKY-UHFFFAOYSA-N
SMILES
CN(CC1=CC=CC=C1)P2OC3=C(C4=CC=CC=C4C=C3)C5=C(O2)C=CC6=CC=CC=C65

Application

Technical Notes:
1. The ligand has been used in Ir- catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines
2. The ligand has been used in the rhodium-catalyzed enanti os elec tive hydrog enation of (E)-N-acylated dehydro-ß- aminoacid esters (For (Z) isomer, use 15-1525)
References :
1.J. Am. Chem. Soc..2010, 132, 2124.
2.J. Am. Chem. Soc., 2002, 124, 14552.

References Data Source From Pubchem

Iridium Catalysts with Monodentate Phosphorus Ligands
Publication Name: Science of Synthesis
Publication Date: 2018

Iridium-Catalyzed Asymmetric Hydrogenation of Benzophenone N–H Imines
Publication Name: Synfacts
Publication Date: 2010-04-22
DOI: 10.1055/s-0029-1219638

Asymmetric Hydrogenation
Publication Name: Science of Synthesis
Publication Date: 2005

Amides
Publication Name: Science of Synthesis
Publication Date: 2005