(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos|15-1234|284472-79-3

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos

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Sku SC15-1234_2_G
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Product Information

Product Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta2,1-a;3,4-a'dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos
Brand Name
US-Strem
Product Number
15-1234
CAS
284472-79-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11429465
IUPAC Name
1-(12,14-dioxa-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl)piperidine
InChI Key
ZYDGLCZCEANEHK-UHFFFAOYSA-N
SMILES
C1CCN(CC1)P2OC3=C(C4=CC=CC=C4C=C3)C5=C(O2)C=CC6=CC=CC=C65

Application

Technical Notes:
1.See 15-1232
2. L igand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of a dehydroaminoesters, enamides, and dimethylitaconate.
3. Ligand used in asymmetric hydrogenation of 2-substituted N-protected indoles using Rhodium-based catalysts.
References:
1.J. Org. Chem.. 2005, 70, 943. 2.Tetrahedron, 2010, 21，7
3.Organometallics, 2011. 30. 1942 4. 4.Adv. Synth. Catal., 2011, 353.

References Data Source From Pubchem

Iridium Catalysts with Monodentate Phosphorus Ligands
Publication Name: Science of Synthesis
Publication Date: 2018

Short and Straightforward Enantioselective Synthesis of Both Enantiomers of Mequitazine through Iridium-Catalyzed Asymmetric Hydrogenation of a Nonfunctionalized Cyclic Enamine
Publication Name: Synlett
Publication Date: 2014-05-14
DOI: 10.1055/s-0033-1341274

Asymmetric Synthesis of Pipecolic Acid and Derivatives
Publication Name: Synthesis
Publication Date: 2012-05-25
DOI: 10.1055/s-0031-1289767

Reduction of Quinoxalines to 1,2,3,4-Tetrahydroquinoxalines
Publication Name: Science of Synthesis
Publication Date: 2012

Iridium-Catalyzed Asymmetric Hydrogenation
Publication Name: Science of Synthesis
Publication Date: 2011