(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%|15-1520|415918-91-1

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%

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Product Information

Product Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta2,1-a;3,4-a'dinaphthalen-4-yl)bis(1R)-1-phenylethylamine, dichloromethane adduct, min. 95%
Brand Name
US-Strem
Product Number
15-1520
CAS
415918-91-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10886035
IUPAC Name
N,N-bis(1R)-1-phenylethyl-12,14-dioxa-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine
InChI Key
LKZPDRCMCSBQFN-CLJLJLNGSA-N
SMILES
CC@H(C1=CC=CC=C1)N(C@H(C)C2=CC=CC=C2)P3OC4=C(C5=CC=CC=C5C=C4)C6=C(O3)C=CC7=CC=CC=C76

Application

Technical Notes:
1. A ligand for as ymmetric conjugate addition of dialkyI zinc reagents to activated olefins .
2.L igand used in the iridium-c atalyzed, enantios elective addition of nucleophiles to achiral
allylic esters
3.As ymmetric hydrogenation.
4.Ir-catalyzed regio- and enantioselective F riedel-Crafts allylic alkylation of indoles .
6.As ymmetric hydrovinylation.
6.Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes," a and
7.Rh-catalyzed 5+2 cycloaddition of alkyne -vinyl-c yclopropanes .
P alladium-catalyzed enantios elective de- epimerization in catalytic asymmetric allylic alkylation. 8. P alladium-catalyzed enantios elective diamination of alkyl dienes .

References Data Source From Pubchem

Strained Alkenes as Ethene Acceptors
Publication Name: Science of Synthesis
Publication Date: 2023

Nonstabilized Carbon Nucleophiles: Silyl Enol Ethers
Publication Name: Science of Synthesis
Publication Date: 2023

State-of-the-Art Advances in Enantioselective Transition-Metal-Mediated Reactions of Silacyclobutanes
Publication Name: Synthesis
Publication Date: 2022-09-21
DOI: 10.1055/a-1929-4890

Copper/Iridium-Catalyzed Cascade Reaction for the Synthesis of α-Deuterated α-Amino Acids
Publication Name: Synfacts
Publication Date: 2022-09-20
DOI: 10.1055/s-0041-1738582

Acyclic Quaternary Carbon Stereocenters through Transition-Metal-Catalyzed Enantioselective Functionalization of Unsaturated Hydrocarbons
Publication Name: Synthesis
Publication Date: 2022-03-01
DOI: 10.1055/s-0040-1719899