(1R,2R)-N,N'-Di-p-tosyl-1,2-diphenyl-1,2-ethylenediamine, min. 98%|07-4060|121758-19-8

(1R,2R)-N,N'-Di-p-tosyl-1,2-diphenyl-1,2-ethylenediamine, min. 98%

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Sku SC07-4060_500_MG
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Product Information

Product Name
(1R,2R)-N,N'-Di-p-tosyl-1,2-diphenyl-1,2-ethylenediamine, min. 98%
Brand Name
US-Strem
Product Number
07-4060
CAS
121758-19-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
2733818
IUPAC Name
4-methyl-N-(1R,2R)-2-(4-methylphenyl)sulfonylamino-1,2-diphenylethylbenzenesulfonamide
InChI Key
SJEDVDWSFHJKIZ-VSGBNLITSA-N
SMILES
CC1=CC=C(C=C1)S(=O)(=O)NC@H(C2=CC=CC=C2)C@@H(C3=CC=CC=C3)NS(=O)(=O)C4=CC=C(C=C4)C

Application

Technical Notes：
1.Lewis acid mediated asymmetric [2,3]-sigmatropic rearrangement of achiral allylic amines.
2.A bidirectional SE' strategy for 1 ,5-syn and 1 ,5-anti ste reocontrol toward the synthesis of complex polyols.
3.Enantioselective synthesis of a furan lignan (+ )-Sylvone.
References:
1. J. Org. Chem., 2007. 72, 1294.
2.Org. Lett., 2012, 14, 3866.
3. J. Org. Chem., 2015, 80, 10359.

References

Cyclization of Vinylselenones and Ethane-1,2-diamines
Publication Name: Science of Synthesis
Publication Date: 2021

Highly Enantioselective Addition of Phenylacetylene to Ketones Catalyzed by Bis(hydroxycamphorsulfonamide)–Copper(II) Complex
Publication Name: Synlett
Publication Date: 2006-03-10
DOI: 10.1055/s-2006-932473

Using Diamino(halo)boranes
Publication Name: Science of Synthesis
Publication Date: 2005

Borylation of Stannanes
Publication Name: Science of Synthesis
Publication Date: 2005