Product Name
(2R)-(-)-N-Methyl-α,α-diphenyl-2-pyrrolidinemethanol, min. 98%
Certificate of Analysis (COA)
IUPAC Name
(2R)-1-methylpyrrolidin-2-yl-diphenylmethanol
InChI Key
XIJAGFLYYNXCAB-QGZVFWFLSA-N
SMILES
CN1CCCC@@H1C(C2=CC=CC=C2)(C3=CC=CC=C3)O
Technical Notes:
1.Microwave assisted aryl transfer to aldehydes using the ligand .
2.Ligand used in the synthesis of enantioenriched a-(hydroxyalkyl)-tri-n-butylstannanes.
3.Catalytic asymmetric arylation of aliphatic aldehydes using a B/Zn exchange reaction.
4.Oxy-allyl cation catalysis: An enantioselective electrophilic activation mode.
References:
1.J. Org. Chem., 2008, 73, 2879.
2.Angew. Chem. Int. Ed., 2008, 47, 6586.
3.Tetrahedron, 2015, 71, 1202.
4.J. Am. Chem. Soc., 2016, 138, 2134.
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