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Sku SC07-0956_50_MG
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General Details
CAS # 479423-21-7
SMILES
Chemical Purity
Molecular Formula C21H34N4OS
Chemical Formula
Formula Weight 390.60
Reaction
Note
Physical Properties
Purity 98%, (99% ee)
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1.Conjugate Addition: Primary amine -thiourea derivative is an active and highly enantioselective catalyst for the conjugate addition of ketones to nitroalkenes.
2.Michael Addition: The asymmetric Michael addition of dioxindoles to ß-substituted nitroalkenes is reported. The bifunctional primary amine-thiourea, by means of a non-covalent-based mode of catalysis, secures
direct access to 3-substituted 3-hydroxyoxindole derivatives with high stereocontrol.
References:
1. J. Am. Chem. Soc., 2006, 128, 7170-7171. 2. Chem. Commun., 2012, 48, 3336-3338.