(1'R,2'R,3aS,3

(1'R,2'R,3aS,3"aS,8aR,8"aR)-(+)-3,3",3a,3"a,8,8",8a,8"a-Octahydrodispiro{2H-indeno[1,2-d]oxazole-2,1'-cyclohexane-2',2"-[2H]indeno[1,2-d]oxazole} WOLF BISOXAZOLIDINE

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Sku SC07-0488_250_MG
US-Strem
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Product Information

Product Name
(1'R,2'R,3aS,3"aS,8aR,8"aR)-(+)-3,3",3a,3"a,8,8",8a,8"a-Octahydrodispiro{2H-indeno1,2-doxazole-2,1'-cyclohexane-2',2"-2Hindeno1,2-doxazole} WOLF BISOXAZOLIDINE
Brand Name
US-Strem
Product Number
07-0488
CAS
947515-50-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
127256148
InChI Key
QRTLPEUTEFJSFH-GDHSQPOBSA-N
SMILES
C1CCC@@2(C@3(C1)NC@@H4C@H(O3)CC5=CC=CC=C45)NC@@H6C@H(O2)CC7=CC=CC=C67

Application

Technical Notes:
1.Catalyst used in the asymmetric addition of diethylzinc to aldehydes - synthesis of chiral alcohols.
2.Catalysts used in the asymmetric addition of acetylenes and silylacetylenes to aldehydes .
3.Catalyst used in the asymmetric addition of nitromethane to aldehydes - synthesis of ß-hydroxynitromethanes.
References:
1.Org. L ett., 2007, 9, 2965.
2.J. Am. Chem. Soc., 2006, 128, 1 0996.
3.Org. L ett., 2008, 10, 1831.