Cat. No JK368234_250_ML
J&K Chemical

Product Information

Product Name
1-Octadecene, 90%, tech.
Brand Name
J&K
Product Number
368234
CAS
112-88-9
Molecular Formula
C18H36
Molecular Weight
252.48
SDS Document
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
8217
IUPAC Name
octadec-1-ene
InChI Key
CCCMONHAUSKTEQ-UHFFFAOYSA-N
SMILES
CCCCCCCCCCCCCCCCC=C

Properties

Density
0.789
Melting Point
14-16
Boiling Point
309 - 319
Flash Point
149
n20D
1.4440

Safety Information

Signal Word
Danger
Hazard Statement
H304
Precautionary Statement
P331
P405
P501
P301+P316

Description

Product Introduction

Oleylamine (CAS No. 112-88-9) is a long-chain primary fatty amine containing an 18-carbon unsaturated hydrocarbon chain and a primary amine group. Its amphiphilic structure provides both surface-active and coordinating properties, making it an important reagent and ligand in nanomaterial synthesis and materials chemistry.

Oleylamine is widely used in nanoparticle synthesis, colloidal nanomaterials, surface modification, catalysis, organic synthesis, and materials research. It can function simultaneously as a solvent, reducing agent, stabilizer, and surface ligand depending on the reaction system.

Its ability to coordinate with metal ions and bind to nanoparticle surfaces makes it particularly valuable for controlling particle size, morphology, dispersion, and surface chemistry.

 

Mechanism / Principle

Surface Ligand and Stabilization Function

Oleylamine contains a primary amine group capable of coordinating with metal ions and metal-containing surfaces, while its long hydrophobic chain provides steric stabilization.

In nanomaterial synthesis:

  • The amine group can coordinate with metal precursors or nanoparticle surfaces.
  • The hydrocarbon chain provides steric stabilization.
  • Surface binding can limit uncontrolled particle aggregation.
  • Reaction conditions involving Oleylamine can influence nucleation and crystal growth.
  • Its dual role as ligand and reaction medium can affect nanoparticle morphology and size distribution.

This makes Oleylamine particularly useful for colloidal synthesis of metal, semiconductor, and metal oxide nanomaterials.

 

Key Research Applications

1. Nanoparticle Synthesis

Oleylamine is widely used in the preparation of colloidal nanoparticles.

Applications include:

  • Metal nanoparticle synthesis
  • Semiconductor nanocrystals
  • Metal oxide nanoparticles
  • Quantum dots
  • Colloidal nanomaterials
  • Size-controlled nanoparticle synthesis

 

2. Quantum Dot Synthesis

Oleylamine is commonly used as a ligand and reaction medium in quantum-dot synthesis.

Applications include:

  • Semiconductor quantum dots
  • Lead chalcogenide nanocrystals
  • Metal chalcogenide nanomaterials
  • Quantum-dot surface modification
  • Colloidal nanocrystal research

Its surface-coordinating properties can help control nanocrystal growth and colloidal stability.

 

3. Metal Nanomaterials

Oleylamine can coordinate with metal precursors and stabilize the resulting nanoparticles.

Applications include:

  • Gold nanoparticles
  • Silver nanoparticles
  • Platinum nanoparticles
  • Copper nanoparticles
  • Metal nanostructure synthesis

 

4. Surface Modification and Ligand Exchange

Oleylamine is useful for modifying the surface chemistry of nanomaterials.

Applications include:

  • Nanoparticle surface functionalization
  • Ligand exchange studies
  • Colloidal stabilization
  • Surface chemistry research
  • Nanomaterial dispersion

 

5. Materials Chemistry

Oleylamine can act as a reaction medium, ligand, and stabilizer in advanced materials synthesis.

Applications include:

  • Nanostructured materials
  • Semiconductor materials
  • Functional nanomaterials
  • Thin-film precursor preparation
  • Materials surface engineering

 

6. Catalysis Research

Oleylamine-stabilized nanoparticles are widely investigated as catalysts and catalyst precursors.

Applications include:

  • Nanocatalyst preparation
  • Heterogeneous catalysis
  • Electrocatalyst synthesis
  • Catalyst surface modification
  • Catalytic materials research

 

7. Organic and Chemical Synthesis

Oleylamine can also be used as a long-chain amine reagent in organic synthesis.

Applications include:

  • Amide formation
  • Amine functionalization
  • Long-chain amine chemistry
  • Organic intermediate synthesis
  • Surface-active molecule synthesis

 

Advantages

  • Long-chain primary amine
  • Strong surface-coordinating ability
  • Useful nanoparticle ligand
  • Provides steric stabilization
  • Suitable as a reaction medium
  • Useful for quantum-dot synthesis
  • Applicable to metal and semiconductor nanomaterials
  • Useful for surface modification
  • Broad applications in materials chemistry

 

Storage & Handling

  • Store in a tightly sealed container.
  • Keep in a cool, dry, and well-ventilated environment.
  • Protect from excessive heat and direct sunlight.
  • Minimize prolonged exposure to air and moisture.
  • For sensitive nanomaterial synthesis applications, storage under an inert atmosphere may be appropriate.
  • Avoid contact with strong oxidizing agents and incompatible chemicals.
  • Handle according to appropriate laboratory safety procedures.
  • Consult the product-specific SDS before use.

 

Research Areas

Researchers working in the following fields may benefit from Oleylamine (CAS No. 112-88-9):

  • Nanomaterials
  • Nanoparticle synthesis
  • Quantum dots
  • Colloidal nanocrystals
  • Materials chemistry
  • Surface chemistry
  • Semiconductor materials
  • Catalysis
  • Organic synthesis
  • Optoelectronic materials

FAQ

Q1: What is Oleylamine?

A: Oleylamine is a long-chain unsaturated primary amine with the molecular formula C₁₈H₃₇N and CAS No. 112-88-9.

 

Q2: What is Oleylamine used for?

A: Oleylamine is widely used in nanoparticle synthesis, quantum-dot preparation, surface modification, materials chemistry, catalysis, and organic synthesis.

 

Q3: What is the molecular weight of Oleylamine?

A: The molecular weight of Oleylamine is approximately 267.50 g/mol.

 

Q4: Why is Oleylamine used in nanoparticle synthesis?

A: Oleylamine can function as a ligand, stabilizer, reducing agent, and reaction medium, depending on the synthesis system. Its amine group can coordinate with metal species while its long hydrocarbon chain provides steric stabilization.

 

Q5: Can Oleylamine be used for quantum-dot synthesis?

A: Yes. Oleylamine is commonly used as a ligand and reaction medium in the synthesis of various colloidal semiconductor nanocrystals and quantum dots.

 

Q6: Is Oleylamine a ligand?

A: Yes. The primary amine group can coordinate with metal ions and nanoparticle surfaces, allowing Oleylamine to act as a surface ligand.

 

Q7: What is the physical form of Oleylamine?

A: Oleylamine is generally supplied as a liquid.

 

Q8: How should Oleylamine be stored?

A: Store tightly sealed in a cool, dry environment and protect it from excessive heat, moisture, and prolonged exposure to air.

References Data Source From Pubchem

Proton shuttle-assisted triplet energy transfer

Publication Name: Nature Materials
Publication Date: 2026-03-09
DOI: 10.1038/s41563-026-02535-4

Cross-validation of analytical methods for citrate ligand quantification on upconversion and iron oxide nanoparticles

Publication Name: Analytical and Bioanalytical Chemistry
Publication Date: 2026-03-04
DOI: 10.1007/s00216-026-06402-8

Molecular Entanglement and Interface Locking by Inorganic Sub-nanowires for Concurrent Mechanical and Piezoelectric Reinforcement in Polymer Composites

Publication Name: Advanced Fiber Materials
Publication Date: 2026-03-04
DOI: 10.1007/s42765-026-00697-z

Multifunctional ligand engineering enables high-performance CsPb(Br/Cl)3 nanocrystals toward efficient and stable pure-blue perovskite LEDs

Publication Name: Light: Science & Applications
Publication Date: 2026-02-28
DOI: 10.1038/s41377-026-02214-8

Engineering Anti-MMP-9 Peptide-Modified Nanoparticles for Precision MRI Diagnosis of Endometriosis

Publication Name: Molecular Imaging and Biology
Publication Date: 2026-02-27
DOI: 10.1007/s11307-026-02086-9

1-Octadecene, 90%, tech.

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